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Scorching goIITian

Joined: 27 Aug 2008
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8 Mar 2010 11:36:48 IST
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calculate pH of mixture of 100ml of 0.1M HCL and 50ml 0.1M Ca(OH)2
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calculate pH of mixture of 100ml of 0.1M HCL and 50ml 0.1M Ca(OH)2


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NugoRama's Avatar

Blazing goIITian

Joined: 11 Mar 2009
Posts: 5517
8 Mar 2010 14:29:01 IST
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100ml of 0.1M HCL and 50ml 0.1M Ca(OH)2

...

H+ ions = n! x volume x molarity = 1 x 0.1 x 100 milli moles = 10 mmoles.

OH- ions = n! x volume x molarity = 2 x 50 x 0.1 = 10 mmoles.

Volume of the solution = 150 ml.

[H+] = [OH-] = 1/15 M

Concentration of both is same ..hence solution is neutral ... Ph = 7.

 

Aliter,

As HCl is monobasic and Ca(oh)2 is diacidic..

Taking equimolar concentrations of both, one volume of Ca(oh)2 neutralises 2 volumes of HCl.

hence, solution is neutral..Hence Ph = 7.

The end.




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