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Organic Chemistry

Bhaskar Tetarbe's Avatar
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24 Apr 2009 12:08:18 IST
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Alkynes question
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Q. Which of these will not react with acetylene ?

a) NaOH           b) ammonical AgNO3       c) Na         d) HCl 


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pranav agrawal's Avatar

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24 Apr 2009 12:32:01 IST
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@ratnesh, thanks a lot for your not so needed advice :P

Bhaskar Tetarbe's Avatar

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24 Apr 2009 12:36:23 IST
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Hey guys dont get heated up.
ratnesh mishra's Avatar

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24 Apr 2009 12:36:51 IST
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@ pranav agrawal i didn't wanted to make u feel bad sorry if i hurt u i was just tellin that i was correct don't take anything personally plzzzz

Bhaskar Tetarbe's Avatar

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24 Apr 2009 12:37:00 IST
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Some experienced Organic experts wud be welcome.
pranav agrawal's Avatar

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24 Apr 2009 12:39:54 IST
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@ ratnesh, thanks once again for your not so needed sympathy for me ~~ i was just completing the concepts u left ~~ yes, i did wrongly said hcl ~~  was just a lil in a sleepy mood power cuts whole night didnt let me sleep   :(


Bhaskar Tetarbe's Avatar

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24 Apr 2009 12:40:58 IST
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So, can anyone conclude the final answer with the proper reason.
ratnesh mishra's Avatar

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24 Apr 2009 12:40:59 IST
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@ pranav agrawal hey dude leave ur attitude somewer & calm down stay cool & then post

Bhaskar Tetarbe's Avatar

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24 Apr 2009 12:41:54 IST
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So, can anyone conclude the final answer with the proper reason.
pranav agrawal's Avatar

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24 Apr 2009 12:42:05 IST
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@ ratnesh, thanks once again for your not so needed sympathy for me ~~ i was just completing the concepts u left ~~ yes, i did wrongly said hcl ~~ was just a lil in a sleepy mood power cuts whole night didnt let me sleep :(
Killer Kiran's Avatar

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24 Apr 2009 12:43:23 IST
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this is the end......................Acetylene has an acidic nature. It means it has an acidic tendency or it can loose proton if provided a suitable reagent (highly basic). It is not a strong acid to react with weak base like Na2CO3. Even NaOH or KOH also does not react. Only Bases like NaNH2 (sodamide) or Tollens reagent and a few other are able to replace H+ of acetylene by the metal atom.H-CC-H + NaNH2 --------------> H-CC-Na + NH3H-CC-H + Ag+ (Tollen's reagent) -------------------> H-CC-Ag + H+In acetylene carbon is sp hybridized. The bond length sp<sp2<sp3. So sp bond is smallest the bonded pair in case of sp hybridized bond is nearer to C than in cases of sp2 snd sp3 bonds. So sp hybridized cabon is more electronegetive and can pull electron more nearer to the carbon and make hydrogen od actylene acquire a little positive charge. Thus the hydrogen become a little acidic in nature but not like hydrogen of an regular acid like CH3COOH and even much less than C2H5OH.

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24 Apr 2009 12:47:17 IST
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got it??



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