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![[Post New]](/templates/default/images/icon_minipost_new.gif) 29 Mar 2008 23:59:46 IST
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Its confusing here. Pyridine does not use its lone pair in delocalization, and C has an electron withdrawing O atom. Both seem to be like almost stable.
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Will nip in at times to solve problems :)
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 30 Mar 2008 11:06:58 IST
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In C the lone pair is in the sp3 orbital but in B the lon pair is in sp2 orbital. Hence the lone pair in B is less available for protonation. Hence it is less basic than C
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"I a universe of atoms.......an atom in the universe" |
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 30 Mar 2008 23:07:23 IST
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I've already answered why C is more basic than B. its due to percentage s-character.
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Happines is like a butterfly;
the more you chase it,
the more it will elude you,
but if you turn you attention to other things,
it will come and sit softly on your shoulders... |
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