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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Basicity order
Forum Index -> Organic Chemistry like the article? email it to a friend.  
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karthik2007 (3349)

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Its confusing here. Pyridine does not use its lone pair in delocalization, and C has an electron withdrawing O atom. Both seem to be like almost stable.

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anandghegde (1707)

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In C the lone pair is in the sp3 orbital but in B the lon pair is in sp2 orbital. Hence the lone pair in B is less available for protonation. Hence it is less basic than C

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iberis22 (575)

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I've already answered why C is more basic than B. its due to percentage s-character.

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