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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: MOCK TEST by BABY RAMDEV
Forum Index -> Organic Chemistry like the article? email it to a friend.  
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anchal_1991 (232)

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TRY DIS


dont worry .
be happy and positive
nd nvr stop bcz life cant wait.
nd watever happens keep smiling bcz log haste huye btr lagte hain.try to fight wid d situation
nd tc of urself bcz u r spl to someone out dere
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ashgirl (1429)

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try wat??

Remember Cedric. Remember, if the time should come when you have to make a choice between what is right and what is easy, remember what happened to a boy who was good, and kind, and brave, because he strayed across the path of Lord Voldemort. Remember Cedric Diggory.


Albus Dumbledore
Goblet of Fire, Chapter 37, Page 724
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anchal_1991 (232)

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try the mock test


dont worry .
be happy and positive
nd nvr stop bcz life cant wait.
nd watever happens keep smiling bcz log haste huye btr lagte hain.try to fight wid d situation
nd tc of urself bcz u r spl to someone out dere
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tarinbansal (3218)

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Thank U very much guys for ur co-operation in keeping this topic alive. I am very greatful to U.
Deadline is tonight between 9-10pm.
So those who want to giv their replies, PLZ mail them before 9 pm.

The quality of a person's life is in direct proportion to their commitment to excellence, regardless of their chosen field of endeavor.

It is during our darkest moments that we must focus to see the light.

Check out my blog at:
http://tarinbansal.blogspot.com/
(A must see for every student)

Back to goiit, this time with Baby Veerappan. :D
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the.sniper (637)

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ya

" The difficult we do immediately, impossible takes a little longer "
--- U.S. Army

"It's better to have a gun and not need it than to need a gun and
not have it."
--- The Sniper

"You can get more with a kind word and a gun than you can with a
kind word. "
--- The Sniper

"Join the Army: travel to exotic distant lands; meet exciting,
unusual people and kill them. "
--- The Sniper

"The victor will never be asked if he told the truth."
--- Adolf Hitler

"Stop talking, start doing"
--- IBM

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the.sniper (637)

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and please dont post the answers before 9 pm as i did.......

" The difficult we do immediately, impossible takes a little longer "
--- U.S. Army

"It's better to have a gun and not need it than to need a gun and
not have it."
--- The Sniper

"You can get more with a kind word and a gun than you can with a
kind word. "
--- The Sniper

"Join the Army: travel to exotic distant lands; meet exciting,
unusual people and kill them. "
--- The Sniper

"The victor will never be asked if he told the truth."
--- Adolf Hitler

"Stop talking, start doing"
--- IBM

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the.sniper (637)

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hello........posted for the sake of reactivation of the thread...... :)

" The difficult we do immediately, impossible takes a little longer "
--- U.S. Army

"It's better to have a gun and not need it than to need a gun and
not have it."
--- The Sniper

"You can get more with a kind word and a gun than you can with a
kind word. "
--- The Sniper

"Join the Army: travel to exotic distant lands; meet exciting,
unusual people and kill them. "
--- The Sniper

"The victor will never be asked if he told the truth."
--- Adolf Hitler

"Stop talking, start doing"
--- IBM

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tarinbansal (3218)

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Alright guys.
The time's up now.
U got full 2 days to do these ques.
Now I am posting the ranks and solutions.

The quality of a person's life is in direct proportion to their commitment to excellence, regardless of their chosen field of endeavor.

It is during our darkest moments that we must focus to see the light.

Check out my blog at:
http://tarinbansal.blogspot.com/
(A must see for every student)

Back to goiit, this time with Baby Veerappan. :D
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the.sniper (637)

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go ahead

" The difficult we do immediately, impossible takes a little longer "
--- U.S. Army

"It's better to have a gun and not need it than to need a gun and
not have it."
--- The Sniper

"You can get more with a kind word and a gun than you can with a
kind word. "
--- The Sniper

"Join the Army: travel to exotic distant lands; meet exciting,
unusual people and kill them. "
--- The Sniper

"The victor will never be asked if he told the truth."
--- Adolf Hitler

"Stop talking, start doing"
--- IBM

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tarinbansal (3218)

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RANKS-
 
 
I- The Sniper
 
Marks=26
 
 
II-Sid.shah.90,Dream
 
Marks=21
 
 
III-Ashgirl
 
Marks=19
 
IV- Ramkumar_november=18
V- Anchal_1991=17
VI- Harsha_27=15
VII- Iitjee08aspirant=13
VIII- atish22=11,rhd92781=11
IX- Fwks_phoenix=8
X- Lampard=6,Rooney=6
XI-Varshavallig=4,Saurabh_reincarnated=4
XII-Abhijeet_0201= -3,Ssk317= -3
XIII-Kbanagar= -10
 

The quality of a person's life is in direct proportion to their commitment to excellence, regardless of their chosen field of endeavor.

It is during our darkest moments that we must focus to see the light.

Check out my blog at:
http://tarinbansal.blogspot.com/
(A must see for every student)

Back to goiit, this time with Baby Veerappan. :D
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tarinbansal (3218)

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Answers-
 
1-A
2-B
3-B
4-B,D
5-A
 
Explanations-
 
1-     The reason to this ques is quite clear. As Cl cant make the compound 3 degree by changing its position, it means methyl group must hav migrated and hence they are chain isomers.
 
 
2-The answer is B becoz of - Hydrogen bonding between -OH and =O , Hyperconjugation as due to restricted rotation, the alkene has 2 alpha H which means 2 hyperconjugative structures and also due to resonance between OH, = , =O.
Some people hav written only resonance, they hav got +1 for the reason not +2 as they hav not explained the complete reason.
 
 
3-Many of U hav given the reason that due to resonance in the molecule, negative charge comes at B so it is the answer. As far as I know, lone pair on N does not participate in resonance as it is not in the plane of pi bonds. Rest of the molecule shows resonance similar to benzene.
I don't think that due to resonance negative charge comes at B. Those who hav said this, must hav taken lone pairs of N in resonance also. PLZ anyone who thinks that negative charge comes at B due to resonance, post the resonance structures here.
Reason- Just break a double bond in + and - and at the position of - , put the electrophile and resonate the + throughout the compound.
U will find that when Electrophile is at A and C, on resonating +, positive charge comes on N which is very unstable and when electrophile is at B, no positive charge comes at N due to resonance so it is most stable.
 
4-Almost all of U got it right. It is an exceptional case in which the last unpaired electron in 3D shell flies off to last orbital of 4p due to strong field nature of ammonia. SO it is paramagnetic and dsp2.
 
5- The best ques of the test and no one has given the 100% correct answer.
The mechanism applied in this ques is called NGP( Neighboring group participation).
Just luk at the figure. As all the C are sp3 hybridised, the chain cannot be a straight chain and its structure is something like I hav shown in the figure.
Now, S has lone pairs which help OH- from KOH to repel Cl and Cl leaves very easily.
U will be surprised to know that the reaction in case of option A is 10000 times faster than that of option B.
 


The quality of a person's life is in direct proportion to their commitment to excellence, regardless of their chosen field of endeavor.

It is during our darkest moments that we must focus to see the light.

Check out my blog at:
http://tarinbansal.blogspot.com/
(A must see for every student)

Back to goiit, this time with Baby Veerappan. :D
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rooney (889)

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lol I must start my organic soon.

http://14-69-8.blogspot.com
My blog
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the.sniper (637)

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yippi.........

" The difficult we do immediately, impossible takes a little longer "
--- U.S. Army

"It's better to have a gun and not need it than to need a gun and
not have it."
--- The Sniper

"You can get more with a kind word and a gun than you can with a
kind word. "
--- The Sniper

"Join the Army: travel to exotic distant lands; meet exciting,
unusual people and kill them. "
--- The Sniper

"The victo