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Tagged with:    [Post New]posted on 27 Mar 2008 07:48:09 IST    
If we mix a weak acid (HA) with its conjugate base (A-), both the acid and base components remain present in the solution. This is because they do not undergo any reactions that significanlty alter their concentrations. The acid and conjugate base may react with one another, HA + A- ? A- + HA, but when they do so, they simply trade places and the concentrations [HA] and [A-] do not change. In addition, HA and A- only rarely react with water. By definition, a weak acid is one that only rarely dissociates in water (that is, only rarely will the acid lose its proton H+ to water). Likewise, since the conjugate base A- is a weak base, it rarely steals a proton H+ from water.
So, the weak acid and weak base remain in the solution with high concentrations since they only rarely react with the water. However, they are very likely to react with any added strong base or strong acid.

If a strong base is added to a buffer, the weak acid will give up its H+ in order to transform the base (OH-) into water (H2O) and the conjugate base: HA + OH- ? A- + H2O. Since the added OH- is consumed by this reaction, the pH will change only slightly...........



If a strong acid is added to a buffer, the weak base will react with the H+ from the strong acid to form the weak acid HA: H+ + A- ? HA. The H+ gets absorbed by the A- instead of reacting with water to form H3O+ (H+), so the pH changes only slightly.......

hope its clear now..........
dont forget 2 leave ur comments...........





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coolriya (456)

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Olaaa!! Perrrfect answer. 84  [102 rates]

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rakesh61 rakesh61 is offline comment by rakesh61    (posted on 27 Mar 2008 08:38:09 IST)
great article Riya something which every student asks after studying buffer keep it up
ridhima ridhima is offline comment by ridhima    (posted on 27 Mar 2008 09:47:12 IST)
its a really good artice with excellent illustration
thanks a lot
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