STATES OF MATTER

There are five main states of matter. Solids, liquids, gases, plasmas, and Bose-Einstein condensates are all different states of matter. Each of these states is also known as a phase. Elements and compounds can move from one phase to another phase when special physical forces are present. One example of those forces is temperature. The phase or state of matter can change when the temperature changes. Generally, as the temperature rises, matter moves to a more active state.

Phase describes a physical state of matter. The key word to notice is physical. Things only move from one phase to another by physical means. If energy is added (like increasing the temperature or increasing pressure) or if energy is taken away (like freezing something or decreasing pressure) you have created a physical change.


One compound or element can move from phase to phase, but still be the same substance. You can see water vapor over a boiling pot of water. That vapor (or gas) can condense and become a drop of water. If you put that drop in the freezer, it would become a solid. No matter what phase it was in, it was always water. It always had the same chemical properties. On the other hand, a chemical change would change the way the water acted, eventually making it not water, but something completely new.

CHANGING STATES OF MATTER

All matter can move from one state to another. It may require very low temperatures or very high pressures, but it can be done. Phase changes happen when certain points are reached. Sometimes a liquid wants to become a solid. Scientists use something called a freezing point to measure when that liquid turns into a solid. There are physical effects that can change the freezing point. Pressure is one of those effects. When the pressure surrounding a substance goes up, the freezing point also goes up. That means it's easier to freeze the substance at higher pressures. When it gets colder, most solids shrink in size. There are a few which expand but most shrink.

Now you're a solid. You're a cube of ice sitting on a counter. You dream of becoming liquid water. You need some energy. Atoms in a liquid have more energy than the atoms in a solid. The easiest energy around is probably heat. There is a magic temperature for every substance called the melting point. When a solid reaches the temperature of its melting point it can become a liquid. For water the temperature has to be a little over zero degrees Celsius. If you were salt, sugar, or wood your melting point would be higher than water.

The reverse is true if you are a gas. You need to lose some energy from your very excited gas atoms. The easy answer is to lower the surrounding temperature. When the temperature drops, energy will be sucked out of your gas atoms. When you reach the temperature of the condensation point, you become a liquid. If you were the steam of a boiling pot of water and you hit the wall, the wall would be so cool that you would quickly become a liquid.

Finally, you're a gas. You say, "Hmmmm. I'd like to become a plasma. They are too cool!" You're already halfway there being a gas. You still need to tear off a bunch of electrons from your atoms. Eventually you'll have bunches of positively and negatively charged particles in almost equal concentrations. When the ions are in equal amounts, the charge of the entire plasma is close to neutral. (A whole bunch of positive particles will cancel out the charge of an equal bunch of negatively charged particles.) A plasma can be made from a gas if a lot of energy is pushed inside. All of this extra energy makes the neutral atoms break apart into positively and negatively charged ions and free electrons. They wind up in a big gaseous ball.

CHEMICAL vs. PHYSICAL CHANGES

It is important to understand the difference between chemical and physical changes. The two types are based on studying chemical reactions and states of matter. We admit that some changes are obvious, but there are some basic ideas you can use. Physical changes are about energy and states of matter. Chemical changes happen on a molecular level.

When you step on a can and crush it, you have forced a physical change. The shape of the object has changed. It wasn't a change in the state of matter, but something changed. When you melt an ice cube you have also forced a physical change (adding energy). That example caused a change in the state of matter. You can cause physical changes with forces like motion, temperature, and pressure.

Chemical changes happen on a much smaller scale. While some experiments show obvious chemical changes such as a color change, most chemical changes happen between molecules and are unseen. When iron (Fe) rusts you can see it happen over a long period of time. The actual molecules have changed their structure (the iron oxidized). Melting a sugar cube is a physical change because the substance is still sugar. Burning a sugar cube is a chemical change. The energy of the fire has broken down the chemical bonds.

Some changes are extremely small. Chemical changes can happen over a series of steps, and the result might have the same number of atoms but have a different structure. The sugars glucose, galactose, and fructose all have six carbon atoms, twelve hydrogen atoms, and six oxygen atoms. Even though they are made of the same atoms, they have very different shapes and are called structural isomers. They each have different chemical reactions because of their molecular structure.

SOLID BASICS

So what is a solid? Solids are usually hard because their molecules have been packed together. The closer your molecules are, the harder you are. Solids also can hold their own shape. A rock will always look like a rock unless something happens to it. The same goes for a diamond. Even when you grind up a solid into a powder, you will see little tiny pieces of that solid under a microscope. Liquids will move and fill up any container. Solids like their shape.

In the same way that a solid holds its shape, the atoms inside of a solid are not allowed to move around too much. This is one of the physical characteristics of solids. Atoms and molecules in liquids and gases are bouncing and floating around, free to move where they want. The molecules in a solid are stuck. The atoms still spin and the electrons fly around, but the entire atom will not change position.

Solids can be made up of many things. They can have pure elements or a variety of compounds inside. When you get more than one type of compound in a solid it is called a mixture. Most rocks are mixtures of many different compounds. Concrete is a good example of a manmade mixture.

CRYSTALS

On the other end of the spectrum from a mixture is something called a crystal. When a solid is made up of a pure substance and forms slowly, it can become a crystal. Not all pure substances form crystals because it is a delicate process. The atoms are arranged in a regular repeating pattern called a cystal lattice. A crystal lattice is a very exact organization of atoms. A good example is carbon. A diamond is a perfect crystal lattice while the graphite arrangement is more random.

LIQUID BASICS

The second state of matter we will discuss is a liquid. Solids are hard things you can hold. Gases are floating around you and in bubbles. What is a liquid? Water is a liquid. Your blood is a liquid. Liquids are an in-between state of matter. They can be found in between the solid and gas states. They don't have to be made up of the same compounds. If you have a variety of materials in a liquid, it is called a solution.

One characteristic of a liquid is that it will fill up the shape of a container. If you pour some water in a cup, it will fill up the bottom of the cup first and then fill the rest. The water will also take the shape of the cup. It fills the bottom first because of gravity. The top part of a liquid will usually have a flat surface. That flat surface is because of gravity too. Putting an ice cube (solid) into a cup will leave you with a cube in the middle of the cup; the shape won't change until the ice becomes a liquid.

Another trait of liquids is that they are difficult to compress. When you compress something, you take a certain amount and force it into a smaller space. Solids are very difficult to compress and gases are very easy. Liquids are in the middle but tend to be difficult. When you compress something, you force the atoms closer together. When pressure go up, substances are compressed. Liquids already have their atoms close together, so they are hard to compress. Many shock absorbers in cars compress liquids in tubes.

A special force keeps liquids together. Solids are stuck together and you have to force them apart. Gases bounce everywhere and they try to spread themselves out. Liquids actually want to stick together. There will always be the occasional evaporation where extra energy gets a molecule excited and the molecule leaves the system. Overall, liquids have cohesive (sticky) forces at work that hold the molecules together.

EVAPORATION OF LIQUIDS

Sometimes a liquid can be sitting in one place (maybe a puddle) and its molecules will become a gas. That's the process called evaporation. It can happen when liquids are cold or when they are warm. It happens more often with warmer liquids. Evaporation is all about the energy in individual molecules, not about the average energy of a system. The average energy can be low and the evaporation still continues.

You might be wondering how that can happen when the temperature is low. It turns out that all liquids can evaporate at room temperature and normal air pressure. Evaporation happens when atoms or molecules escape from the liquid and turn into a vapor. Not all of the molecules in a liquid actually have the same energy.

The energy you can measure with a thermometer is really an average of all the molecules in the system. There are always a few molecules with a lot of energy and some with barely any energy at all. The molecules with a lot of energy are able to build up enough power to become a gas. Once they reach that energy level, they can leave the liquid. When the molecule leaves, it has evaporated.
The rate of evaporation can also increase with a decrease in the gas pressure around a liquid. Molecules like to move from areas of higher pressure to lower pressure. The molecules are basically sucked into the surrounding area to even out the pressure. Once the vapor pressure of the area increases to a specific level, the rate of evaporation will slow down.

PLASMA BASICS

Plasmas are a lot like gases, but the atoms are different because they are made up of free electrons and ions of the element. You don't find plasmas too often when you walk around. They aren't things that happen regularly on Earth. If you have ever heard of the Northern Lights or ball lightning, you might know that those are types of plasmas. It takes a very special environment to keep plasmas going. They are different and unique from the other states of matter.

FINDING A PLASMA

You won't find plasmas just anywhere. However, there may be some in front of you. Think about a fluorescent light bulb. They are not like regular light bulbs. Inside the long tube is a gas. Electricity flows through the tube when the light is turned on. The electricity acts as that special energy and charges up the gas. This charging and exciting of the atoms creates glowing plasma inside the bulb.

Another example of plasma is a neon sign. Just like a fluorescent light, neon signs are glass tubes filled with gas. When the light is turned on, the electricity flows through the tube. The electricity charges the gas, possibly neon, and creates plasma inside of the tube. The plasma glows a special color depending on what kind of gas is inside.

You also see plasma when you look at stars. Stars are big balls of gases at really high temperatures. The high temperatures charge up the atoms and create plasma. Stars are another good example of how the temperature of plasmas can be very different. Fluorescent lights are cold compared to really hot stars. They are still both forms of plasma, even with different physical characteristics.

BOSE-EINSTEIN BASICS

This state of matter was the only one created while you were alive. In 1995, two scientists, Cornell and Weiman, finally created this new state of matter. Two other scientists, Satyendra Bose and Albert Einstein, had predicted it in the 1920. They didn't have the equipment and facilities to make it happen in the 20s. Now we do. If plasmas are super hot and super excited atoms, the atoms in a Bose-Einstein condensate (BEC) are total opposites. They are super-unexcited and super-cold atoms.

ABOUT CONDENSATION

Let's explain condensation first. Condensation happens when several gas molecules come together and form a liquid. It all happens because of a loss of energy. Gases are really excited atoms. When they lose energy, they slow down and begin to collect. They can collect into one drop. Water condenses on the lid of your pot when you boil water. It cools on the metal and becomes a liquid again. You would then have a condensate.

The BEC happens at super low temperatures. We have talked about temperature scales and Kelvin. At zero Kelvin all molecular motion stops. Scientists have figured out a way to get a temperature only a few billionths of a degree above absolute zero. When temperatures get that low, you can create a BEC with a few special elements. Cornell and Weiman did it with Rubidium.

LET THE CLUMPING BEGIN

So it's cold. A cold ice cube is still a solid. When you get to a temperature near absolute zero something special happens. Atoms begin to clump. The whole process happens at temperatures within a few billionths of a degree so you won't see this at home. The result of this clumping is the BEC. A group of atoms takes up the same place, creating a "super atom." There are no longer thousands of separate atoms. They all take on the same qualities and for our purposes become one blob.

 

SOLUTIONS AND MIXTURES

Before we dive into solutions, let's separate solutions from other types of mixtures. Solutions are groups of molecules that are mixed up in a completely even distribution. Hmmm. Not the easiest way to say it. Scientists say that solutions are homogenous systems. Other types of mixtures can have a little higher concentration on one side of the liquid when compared to the other side. Solutions have an even concentration throughout the system. An example: Sugar in water vs. Sand in water. Sugar dissolves and is spread throughout the glass of water. The sand sinks to the bottom. The sugar-water could be considered a solution. The sand-water is a mixture.

CAN ANYTHING BE IN SOLUTION?

Pretty much. Solutions can be solids dissolved in liquids. They could also be gases dissolved in liquids (such as carbonated water). There can also be gases in other gases and liquids in liquids. If you mix things up and they stay at an even distribution, it is a solution. You probably won't find people making solid-solid solutions in front of you. They start off as solid/gas/liquid-liquid solutions and then harden at room temperature. Alloys with all types of metals are good examples of a solid solution at room temperature. A simple solution is basically two substances that are going to be combined. One of them is called the solute. A solute is the substance to be dissolved (sugar). The other is a solvent. The solvent is the one doing the dissolving (water). As a rule of thumb, there is usually more solvent than solute.

MAKING SOLUTIONS

So what happens? How do you make that solution? Mix the two liquids and stir. It's that simple. Science breaks it into three steps. When you read the steps, remember... Solute=Sugar, Solvent=Water, System=Glass.

1. The solute is placed in the solvent and the concentrated solute slowly breaks into pieces.
2. The molecules of the solvent begin to move out of the way and they make room for the molecules of the solute. Example: The water has to make room for the sugar molecules.
3. The solute and solvent interact with each other until the concentration of the two substances is equal throughout the system. The concentration of sugar in the water would be the same from a sample at the top, bottom, or middle of the glass.

CAN ANYTHING CHANGE SOLUTIONS?

Sure. All sorts of things can change the concentrations of substances in solution. Scientists use the word solubility. Solubility is the ability of the solvent (water) to dissolve the solute (sugar). You may have already seen the effect of temperature in your classes. Usually when you heat up a solvent, it can dissolve more solid materials (sugar) and less gas (carbon dioxide). Next on the list of factors is pressure. When you increase the surrounding pressure, you can usually dissolve more gases in the liquid. Think about your soda can. They are able to keep the fizz inside because the contents of the can are under higher pressure. Last is the structure of the substances. Some things dissolve easier in one kind of substance than another. Sugar dissolves easily in water; oil does not. Water has a low solubility when it comes to oil.

MIXTURE BASICS

Mixtures are absolutely everywhere you look. Mixtures are the form for most things in nature. Rocks, air, or the ocean, they are just about anything you find. They are substances held together by physical forces, not chemical. That statement means the individual molecules enjoy being near each other, but their fundamental chemical structure does not change when they enter the mixture.

When you see distilled water, it's a pure substance. That fact means that there are just water molecules in the liquid. A mixture would be a glass of water with other things dissolved inside, maybe salt. Each of the substances in that glass of water keeps the original chemical properties. So, if you have some dissolved substances, you can boil off the water and still have those dissolved substances left over. Because it takes very high temperatures to boil salt, the salt is left in the container.

MIXTURES ARE EVERYWHERE

There are an infinite number of mixtures. Anything you can combine is a mixture. Think of everything you eat. Just think about how many cakes there are. Each of those cakes is made up of a different mixture of ingredients. Even the wood in your pencil is considered a chemical mixture. There is the basic cellulose of the wood, but there are also thousands of other compounds in that pencil.

Solutions are also mixtures. If you put sand into a glass of water, it is considered to be a mixture. You can always tell a mixture because each of the substances can be separated from the group in different physical ways. You can always get the sand out of the water by filtering the water away. A solution can also be made of two liquids. Even something as simple as bleach and water is a solution.

 

ALLOYS

There are a few more words you might hear when people talk about mixtures. We can't cover all of them, but we'll give you a quick overview of the biggies. Alloys are basically a mixture of two or more metals. Don't forget that there are many elements on the periodic table. Elements like calcium (Ca) and potassium (K) are considered metals. Of course, there are also metals like silver (Ag) and gold (Au). You can also have alloys that include small amounts of non-metallic elements like carbon (C). Metals are the key thing to remember for alloys.

The main idea with alloys is that they are better at something than any of the metals would be alone. Metallurgists (people who work with metals) sometimes add chromium (Cr) and/or nickel (Ni) to steel. While steel is already an alloy that is a very strong metal, the addition of small amounts of the other metals help steel resist rusting. Depending on what element is added, you could create Stainless Steel or Galvanized Steel. It's always about improving specific qualities of the original. Another good example of an alloy happens when metallurgists add carbon (C) to steel. A tiny amount of carbon (a non-metallic element) make steel stronger. These special carbon-steel alloys are used in armor plating and weapons.

AMALGAMS

Amalgams are a special type of alloy. We like them because we think mercury (Hg) is a cool element. You might know mercury as "quicksilver" or the metal that is liquid at room temperature. Anyway, amalgams are alloys that combine mercury and other metals in the periodic table. The most obvious place you may have seen amalgams is in old dental work. The fillings in the mouths of your grandparents may have been amalgams. We already talked about mercury's being a liquid at room temperature. That physical trait was used when they made fillings. Let's say you have an amalgam of mercury (Hg) and silver (Ag). When it is created, it is very soft. As time passes, the mercury leaves the amalgam and the silver remains. The silver that is left is very hard. Voila! You have a filling!

NOTE: Never, ever, play with mercury (Hg)! It is very poisonous. You shouldn't even touch it because it will seep into your skin. Dentists don't usually use amalgams with mercury anymore because it may have slowly poisoned people and gotten them sick.

EMULSIONS

Let's finish up with a little information on emulsions. These special colloids (another type of mixture) have a mixture of oils and waters. Think about a bottle of salad dressing. Before you mix it, there are two separate layers of liquids. When you shake the bottle, you create an emulsion. As time passes, the oil and water will separate to their original states

 

MIXTURES AROUND YOU

Two classic examples of mixtures are concrete and salt water. If you live near the ocean, they surround you every day. Even if you're inland, you need to remember your tap water also has many compounds inside, and they act the same way salt would. That is, concrete is a mixture of lime (CaO)/cement, water, sand, and other ground-up rocks and solids. All of these ingredients are mixed together. Workers then pour the concrete into a mold and the concrete turns into a solid (because of the cement solidifying) with the separate pieces inside.

While the cement hardening might be a chemical reaction, the rocks and gravel are held in place by physical forces. They are included in the mixture to increase the strength of concrete. The rocks and gravel are not chemically bonded to the cement. The gravel is also not evenly distributed. There are pieces of gravel here and there. The concentrations of gravel change from area to area. Salt water is different. First, it's a liquid. Second, it's an ionic solution. The salt is broken up into sodium (Na) and chloride (Cl) ions in the water.

You might be wondering why concrete and salt water are not new compounds when they are mixed together. The special trait of mixtures is that physical forces can still remove the basic parts. You can take the solid concrete and grind it up again. The individual components can then be separated and you can start all over. Salt water is even easier. All you have to do is boil the water off and the salt is left, just as if you never mixed the two compounds.

PUTTING TOGETHER AND BREAKING APART

The thing to remember about mixtures is that you start with some pieces, combine them, and then you can do something to pull those pieces apart again. You wind up with the same molecules (in the same amounts) that you started with. The way you separate the molecules is as unique as the mixture. We have talked about grinding and boiling. If you have a mixture of salt and tiny pieces of iron, you could use a magnet to separate the iron from the mixture.