TemperatureRelation between Celsius and fahrenhite scale is
T
F=9/5 T
C + 32°
T
F - Fahrenhite Temperature
T
C - Celsius Temperature
Relation between Celsius and kelvin scale is
T
C = T
K - 273.15 K
T
K - Temperature in Kelvin
T
C - Temperature in celsius
- If R
0 & R
100 are resistance of metak wire at ice and steam point resp then temp t can be defined corresponding to resistance R
T as follows
- The pressure,volume and temperature in kelvin of such gases obey the equation
PV=nRT ----(1)
Thermal expansion
?L=?L?T
Specific Heat CapacityGas LawsBoyles Law: PV=constant
Charles Law : V/T=constant
Dalton Law of Partial Pressure: P=P
1 + P
2 +P
3Root mean Square Velocity
V
rms=?3RT/M
Mean Square VelocityV
m=?8RT/πM
Average VelocityV=?2RT/M
Also
Vrms >
Vm >
VAverage kinetic Energy of Gas=3/2nRT
First law of Thermodynamics?U=Q-W
Gas ProcessesIsothermal Process : PV=constant ,?U=0,Q=W,Molar Specific Heat=infinity
Adaibatic Process : PV
y=constant,Q=0,?U=-W,Molar Specific Heat=zero
Polytropic Process : PV
n=constant,Molar Specific Heat=R/y-1 + R/1-n
Volume Constant : P/T=constant W=0,?U=Q,Molar Specific Heat=C
vPressure Constant : V/T=constant ?U=Q-W ,Molar Specific Heat=C
PInternal energy depends on Temperature.So for same temperature change ?T
nC
v?T=Q
1-W
1=Q
2-W
2=Q
3-W
3Molar Specfic Heat Capacity of any process is given byC=C
v + Pdv/ndT where n is no of moles of the gas
Workdone by Gas= ?PdV
Heat ConductionQ=-KAdT/dx
Wein displacement law?T
4=Constant
Stefan's LawQ=e?T
4Newton law of CoolingdT/dx=b(T-T
s)