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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Thermodynamics/Fluids question
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konichiwa2x (2224)

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A glass sphere of volume 7litres contains air at 300K. It is connected to a pipe filled with mercury as shown in the figure. At the start, the mercury meniscus is level with the bottom of the sphere on both arms of the pipe. The air in the sphere is now heated and the mercury level on the right arm rises by 5mm. If the cross sectional area of the pipe is 10cm^2, what is the new temperature of the air ?
 
img403/6254/thermqd2.jpg
 

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Conjurer (497)

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=> Mercury level goes down by 5 mm below the bottom of the sphere.

Now because the right end is open to atmosphere so pressure initially in the sphere is also equal to the pressure at the top most point of the right end = 76mm of HG

Increase in pressure = 5mm of mercury.

No. of moles is constant.So equate them with new values of P and V

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karthik2007 (3296)

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Volume of air is constant here.

Hence, using ideal gas equation, we get VdP = nRdT

Now, find dP, as you have been given the increase in the head. Hence, find dT

Required answer is 300+dT

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anchitsaini (4268)

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mbox{ increase in pressure }= dP = hdg \ \ = 5*10^{-3} * 13.6 * 10^3 * 10 = 136 *5Pa \ \ mbox { now }PV = nRT \ \ mbox{ on differentiating } PdV + VdP = nRdT \ \ mbox{as dV = 0 }\ \ VdP = nR dT ....1\ \ mbox{Also at 300K , volume occupied by 1 mole of gas }= rac{22.4*300}{273} \ \ mbox{hence number of moles of gas occupying 7 l of gas at 300K } =  rac{7*273}{22.4*300}\ \=0.28 = n \ \ mbox{putting this value in eqn 1,  }\ \7*10^{-3}*{136*5} = 0.28*8.314*dT \ \ dT = 2K\ \ T = 302K

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Conjurer (497)

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Continuing my solution, since people are posting different approaches :)

(76 * 7)/R 300 = 76.5 * (7.005)/RT :EDIT Thnx to anchint

Solving we get T  = 302.2K app

Whats wrong with my method?

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konichiwa2x (2224)

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seems correct.....I was thinking along anchit's lines...Whats the flaw in that?
i doubt whether the increase in volume (0.005l) would bring about so much change..

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karthik2007 (3296)

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Yes, you are right there.

Will nip in at times to solve problems :)
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anchitsaini (4268)

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i think conjurer's soln is correct now

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anchitsaini (4268)

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ok got it
i think my solution is also right cos even if we take into account PdV in the line before eqn 1 its value would be so small that the difference in the answer in the end would be of around 0.25K (i calculated it)

in conjurer's soln,
he has made mistake in taking P2 = 81 ,it is actually 76.5 cm
and now his answer would also come to be the same i think

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anandghegde (1697)

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@anchit
WTh cant your bear change his dance??? I have been wasting my time watching your bear hoping that he would do some new steps...MadMadMad

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anchitsaini (4268)

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lol
anand you really have high hopes !!

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konichiwa2x (2224)

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good work anchit...thanks!
 

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