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svj29 (2128)

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which fumes in air?
a. BeCl2
b.MgCl2
c.CaCl2
d.BaCl2
 
when Na is heated in moist air, the product obtained is:
1. Na2O
2. NaOH
3. Na2CO3
4. NaO...
 
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rakesh61 (1898)

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ans of 2nd one will be 2

Na + H2O > NaOH + H2

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rakesh61 (1898)

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Ans of 1 st will be MgCl2 as Mgcl2 has weak covalent character it decomposes in moist air to form HCl which gives fume

Please do rate if i m correct or else tell me

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svj29 (2128)

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well sry d ansr 4 d 1st one is given as BeCl2 n 4 d 2nd one is given as Na2O...i 2 thought the same bt d ansrs given r different...

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tarinbansal (3898)

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The second answer is quite obvious and logical.
See the reduction potential of Na is much much less than that of H, hence it cant oxidise H as so the answer given by Rakesh is wrong.
Probability of formation of Na2CO3 is very less as when the ques is saying moist air, it demands some reac between Na,H2O,O not CO2
And formation of a simple oxide is much more favourable than that of a peroxide(NaO).
Hence the answer is Na2O.

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svj29 (2128)

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u cn't count out NaOH like dat only...u knw when Na is exposed to air dn 1st it forms Na2O and then when it reacts with H2O it forms NaOH and when it comes in cntct with CO2 dn it forms Na2CO3...
i'm sure about d above data...but its for air.......
NOT 4 moist one...and if the air is moist dat is dere is more cntent of H20 so NaOH cn't be neglected dere shud be sum rsn....

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tarinbansal (3898)

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I counted out NaOH becoz in the reaction it was forming H2, means it was oxidising H which is not possible.
I didnot do that without reason. I applied redox and electrochem there.

Reactivity series-
Li
Khud dekh lo Na kitna peechhe hai H ke. It cant oxidise H.

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rakesh61 (1898)

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sorry in 1st one my reason is correct but i made a mistake as per fajan rule Be cl is more covalent as size of Be less than mg
Sorry

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tarinbansal (3898)

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arre yeh series likhi kyon nahi aayi?

Li

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tarinbansal (3898)

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Hadd hai yaar. Do baar likhi, ek bhi baar poori nahi aayi.
Kaisa bekar system hai goiit ka.
 
Li < K < Ba < Ca < Na < Mg < Al < Zn < Fe < Ni < Sn < Pb <  H

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