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![[Post New]](/templates/default/images/icon_minipost_new.gif) 20 May 2008 21:06:42 IST
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how do d-orbitals split up in a square planar ligand field according to CFT?
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20 May 2008 23:46:11 IST
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accn to cft,in a square planar complex,the degenerate d orbitals break up in2 a stable t2g set with lower energy content and a relatively unstable eg set with higher energy content.
t2g set contains the d(xy),d(xz),d(yz)
while the eg set contains d(z^2) and d(x^2-y^2)
however,the correct sequence of the orbitals aftr splitting in a sq planar complex is (decreasing energy order)
d(x^2-y^2)
d(xy)
d(z^2)
d(xz)=d(yz)
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"Many of the things you can count,dont count....
Many of the things you cant count,really do count...."-Albert Einstein
"The important thing in science is not so much to obtain new facts as to discover new ways of thinking about them"-William Bragg
"An inexplicable fact is infinitely preferable to an incomprehensible mystery"-F. Soddy
RISHIPRATIM MAZUMDAR
NIT DURGAPUR
1ST YEAR,ELECTRONICS AND COMMUNICATIONS
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