sign up I login
 advanced
refer a friend - earn nickels!!

Ask & Discuss Questions with Community & Experts

Moderation Team
 90 chars left    advanced
Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Diels alder reaction
Forum Index -> Organic Chemistry like the article? email it to a friend.  
Author Message
GopalKrishna (18)

New kid on the Block

Olaaa!! Perrrfect answer. 2  [6 rates]

GopalKrishna's Avatar

total posts: 26    
offline Offline

in diels alder reaction , consider a case when the dinucleophile is not a cyclic struture(eg cis- 1,3 buta diene) and reacts with a diene(ethene) to form a non aromatic cyclic structure. Now how is this reaction feaseble ! in the product the C-C bond angle is decreased below that of the original dinucleophile ! there also no resonance to stablilize this ! so why does this reaction take place????????


    
norton (80)

Hot goIITian

Olaaa!! Perrrfect answer. 10  [25 rates]

norton's Avatar

total posts: 103    
offline Offline

um...according to me, this reaction DOES NOT take place...there is no electron withdrawing group attached to ethene...so what's the enophile???  


experts, correct me if i am wrong. 


Alcohol and Calculus -- DON'T MIX -- Please don't Drink and Derive!!!

A committee is a group of people who individually can do nothing but together can decide that nothing can be done.

MUNNA BHAI: Circuit, bole toh yeh Ford kya hai?
CIRCUIT: Bhai, gaadi hai.
MUNNA BHAI: Toh phir, yeh Oxford kya hai?
CIRCUIT: Bole toh, simple hai bhai, Ox mane Bael, Ford mane gaadi. Oxford bole toh Baelgaadi.
 this reply: 0 points  (with Olaaa!! Perrrfect answer.   in 0 votes )   [?]
 
You have to be logged on to rate
  
 
Forum Index -> Organic Chemistry
Go to:   

Top Offers for goIITians
Correspondence Courses
Brilliant Tutorials
Narayana Institute
Aakash Institute
Classroom/Crash Courses
Narayana - Kota , Delhi , Others
Brilliant Tutorials - Class , Crash
Aakash Institute - Medical , Engg
Online Test Series
Brilliant Tutorials
Narayana Institute
Aakash Institute
Mahesh Tutorials
AMITY      Sri Chaitanya