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Organic Chemistry

Hot goIITian

Joined: 13 Jun 2008
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7 Jul 2008 19:31:27 IST
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explain phenol has smaller dipole moment than methanol
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explain phenol has smaller dipole moment than methanol


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Tarin Bansal's Avatar

Blazing goIITian

Joined: 27 Jul 2007
Posts: 3134
7 Jul 2008 20:00:48 IST
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Use vectors.


In phenol, both Phenyl ring and OH have an electron withdrawing effect.


In methanol, Me has electron pushing whereas OH has electron withdrawing effect.


Blazing goIITian

Joined: 3 May 2008
Posts: 779
7 Jul 2008 20:33:33 IST
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In phenol, the lone pairs of oxygen are spread out over the ring due to resonance.
Tarin Bansal's Avatar

Blazing goIITian

Joined: 27 Jul 2007
Posts: 3134
7 Jul 2008 20:41:18 IST
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Well, ya.
Reason given by juana is also right.



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