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![[Post New]](/templates/default/images/icon_minipost_new.gif) 1 Oct 2008 00:55:24 IST
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Why inductive effect of H is assumed to be zero ?????????????
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"You need a perfect strategy to clear JEE more than knowledge " |
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 1 Oct 2008 01:05:26 IST
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one q for u :
y we assume 1amu =1.6*10^(-27) kg
in d same way as we need sumthing ............as base so taht we may compare it widothers that's y
we take inductive effct of H as zero so dat we may derive d inductive effct of others incomparison wid it
correct me if m wrng !
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don't walk as if u rule d world
walk as if u dont care who rules d world
-this is knw as attitude
B who u r and say wat u feel ......
coz those who mind don't matter ........
and those who matter dont mind ......... :)
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 1 Oct 2008 17:08:01 IST
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For measurement of relative inductive effect, hydrogen is chosen as reference in the molecule CR3-H as standard. If, when the hydrogen atom in this molecule is replaced by Z ( an atom or group), the electron density in the CR3 part of the molecule is less in this part than CR3-H, then Z is said to have a -I effect ( electron attracting or electron withdrawing. If the electron density in the CR3 part is greater than in CR3-H, then Z is said to have a + I effect( electron repelling or electron releasing). Thus hydrogen being taken as reference, its inductive effect is naturally assumed as zero.
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