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Organic Chemistry

Rajat Dixit's Avatar
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27 Oct 2007 15:33:38 IST
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Isobutylene is more stable than cis-2-butene.Why ?
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Isobutylene is more stable than cis-2-butene.Why ?


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deeksha cool's Avatar

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Joined: 22 Oct 2007
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27 Oct 2007 17:02:30 IST
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which type of stability r u referring.
plz mention it clearly.
arun-rashi's Avatar

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27 Oct 2007 18:40:36 IST
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in case of isobutylene there is 6 hyperconjugative structure from same side methyl group but in case of 2-butene there is also 6 hyperconjugation but from opposite side so some part cancel out so it is less stable than isobutylene.
Anshuman Bhujabal's Avatar

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28 Oct 2007 06:10:57 IST
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Well I am not too sure of that...
Does hyperconjugative effect ever cancel out????

I would also like that trans 2-butene is more stable than cis 2-butene but is it more stable than isobutene too????



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