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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: nomenclature:Rates Assured
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audittn8 (0)

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Guys , I have this real big confusion abt the following nomenclature terms,
what do you mean by,
NEO
ISO
TERT
SEC Carbons compounds
PLS GIVE THE BASIC IDEA .
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anandghegde (1712)

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iso-1 methyl group attached to 2nd carbon atom of parent chain
neo-2 methyl groups attached to 2nd carbon atom of parent chain


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anandghegde (1712)

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tert refers to tertiary carbon.
sec refers to secondary carbon


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apurviitjee2008 (1399)

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let me give u a simple example.
consider a hydrocarbon with four carbons, C4H10. This molecule can be represented as a straight-chain
(common name: n-butane, IUPAC* name: butane)

or as a branched molecule

or CH3-CH-(CH3)2

(common name: isobutane, IUPAC name: 2-methylpropane or just methylpropane; the 2 is redundant since there is no other place for a branch to go.)

These molecules both have the same chemical formula but are obviously different in their connectivity (structure). They are structural isomers of each other.

If we consider a five-carbon alkane, we can have three different isomers.

CH3-CH2-CH2-CH2-CH3 ====> n-pentane
CH3-CH2-CH-CH3 ====> iso-pentane alias 2-methylbutane
| or simply methylbutane
CH3
CH3
|
CH3- C - CH3 ====> neo-pentane or 2,2-dimethylpropane
|
CH3
These three molecules are all structural isomers of each other, i.e., they all have the formula C5H12 but they have different connectivities (structures).

note that n is not same as neo
tertiary indicates 3 degree carbon and secondary 2 degree carbon
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svj29 (2140)

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The alkanes having a straight or normal chain are called normal or n- hydrocarbons.
The alkanes in which the carbon chain has branches are called branched chain hydrocarbons. Such alkanes as possess a one-carbon branch on the 2nd carbon of the normal basic chain, are called Iso hydrocarbons.
When the normal carbon chainpresent in the molecule has 2 one-carbon branches on the 2nd carbon from the end, the alkane is referred to as Neo hydrocarbon.
Secondary or 2degree carbon atom is the one which is bonded to 2 other carbon atoms.
Tertiary or 3 degree carbon atom is the one which is bonded to 3 other carbon atoms.

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nandinis_7 (16)

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i think the stru formula 4 neo is
 
                       
                         CH3
                          / 
                3HC -C-CH2-R       (where R Is any grp)
                        /
                       CH3
plz correct me if m rong...
 
 
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svj29 (2140)

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no u're wrong bcoz if R is any functional grp containing Carbon then 1st priority will be given to it...
and the name will completely change.

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younggenius (41)

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iso has a methyl group attached to 2nd carbon
neo has 2 methyl groups attached to 2nd carbon
tert is the name given to a compound having functional group at tertiary carbon and similarly for sec
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