IIT JEE , AIEEE Forum - Chemistry , Organic Chemistry

paninimohan

Hi.I am now in class 11 . can any one just tell me a easy way how to remember nomenulature easily? other than mugging? please

hsg2189

you can get the basic names of alkanes upto say decane. then other groups are easy make a chart and read it anytime ur free. i got it same way. am in 12th now!!

put the chart where u can easily read it!!

rate me if u liked it.....

Aatish

The only thing which can help u is PRACTISE and nothing else......
U r right that we don't need to mug up any thing...but u have practise it then u will become an expert in nomenclature.........

Do rate if liked.........

dheer_07

i think u must go through chart once n just start doing questions n u will automatically start remembering it will set in ur mind

seriously it worked when i studied iupac in my xi

sanyogita2023

ya as every body says here dat only prctise is the thng vch can make u perfect in field of nomenclature,,,,,,,,,,,,,,,bt wat i want to say is this is first of all take a general introduction of sigma and pie bonds,carbon covalency,naming of gen. alkanes,alkenes and alkynes and den set the functional groups as thier structure, prefix and sufix........after taking all these thngs in ur glance............dnt take ny of the book.............if u knw the rules.........if u dnt knw the rules then u should prefer book only for rules den strat making a carbon chain according to ur choice.........start frm single chain and do it urself.........and then get it checked by ur teachers..........and by using his method i thnk u can make ur nomenclature side vry strong as i learned it in class IX and i had chosen the way vch i told u ............even do u knw i used to make drawing by using carbon chain and so many thngs...............so try this............and if u r having ny doubt abt rules u can ask me here only ..............i m always here to help u............

in a conclusion i want to say dat.........MAKE ALL THE RULES CLEAR FIRST THEN START MAKING COMPOUNDS FRM URSELF AND TRY TO GV NAME TO IT.........................BEST OF LUCK TO U

As i knw u hav the will power to do it.............

nunoxic

are u talking about specific nomenclature (as in u r given all the carbon compounds and u r asked to mug it ?) or like u open a chapter and there u cant understand nomenclature ??

basically...... u dont have to study nomenclature specially........atleast i dont and so do my friends.....when u open a chapter.........the first part is usually nomenclature......tab ka tab kar lena.......aisa alag chapter padhna is not feasible.....if its there in ur portion......then just go thru some NCERT 12th ka organic chem and nomenclature given for specific compounds (like for eg. Ketones....)

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elessar_iitkgp

The IUPAC nomenclature system is a set of logical rules devised and used by organic chemists to circumvent problems caused by arbitrary nomenclature. Knowing these rules and given a structural formula, one should be able to write a unique name for every distinct compound. Likewise, given a IUPAC name, one should be able to write a structural formula. In general, an IUPAC name will have three essential features:

? A root or base indicating a major chain or ring of carbon atoms found in the molecular structure.
? A suffix or other element(s) designating functional groups that may be present in the compound.
? Names of substituent groups, other than hydrogen, that complete the molecular structure.

Alkanes

Hydrocarbons having no double or triple bond functional groups are classified as alkanes or cycloalkanes, depending on whether the carbon atoms of the molecule are arranged only in chains or also in rings. Although these hydrocarbons have no functional groups, they constitute the framework on which functional groups are located in other classes of compounds, and provide an ideal starting point for studying and naming organic compounds. The alkanes and cycloalkanes are also members of a larger class of compounds referred to as aliphatic. Simply put, aliphatic compounds are compounds that do not incorporate any aromatic rings in their molecular structure.
The following table lists the IUPAC names assigned to simple continuous-chain alkanes from C-1 to C-10. A common "ane" suffix identifies these compounds as alkanes. Longer chain alkanes are well known, and their names may be found in many reference and text books. The names methane through decane should be memorized, since they constitute the root of many IUPAC names. Fortunately, common numerical prefixes are used in naming chains of five or more carbon atoms.

Name	Molecular Formula	Structural Formula	Isomers	Name	Molecular Formula	Structural Formula	Isomers
methane	CH₄	CH₄	1	hexane	C₆H₁₄	CH₃(CH₂)₄CH₃	5
ethane	C₂H₆	CH₃CH₃	1	heptane	C₇H₁₆	CH₃(CH₂)₅CH₃	9
propane	C₃H₈	CH₃CH₂CH₃	1	octane	C₈H₁₈	CH₃(CH₂)₆CH₃	18
butane	C₄H₁₀	CH₃CH₂CH₂CH₃	2	nonane	C₉H₂₀	CH₃(CH₂)₇CH₃	35
pentane	C₅H₁₂	CH₃(CH₂)₃CH₃	3	decane	C₁₀H₂₂	CH₃(CH₂)₈CH₃	75

Some important behavior trends and terminologies:

(i) The formulas and structures of these alkanes increase uniformally by a CH₂ increment.
(ii) A uniform variation of this kind in a series of compounds is called homologous.
(iii) These formulas all fit the C_nH_2n+2 rule. This is also the highest possible H/C ratio for a stable hydrocarbon.
(iv) Since the H/C ratio in these compounds is at a maximum, we call them saturated (with hydrogen).

Beginning with butane (C₄H₁₀), and becoming more numerous with larger alkanes, we note the existence of alkane isomers. For example, there are five C₆H₁₄ isomers, shown below as abbreviated line formulas (A through E):

Although these distinct compounds all have the same molecular formula, only one (A) can be called hexane. How then are we to name the others?

The IUPAC system requires first that we have names for simple unbranched chains, as noted above, and second that we have names for simple alkyl groups that may be attached to the chains. Examples of some common alkyl groups are given in the following table. Note that the "ane" suffix is replaced by "yl" in naming groups. The symbol R is used to designate a generic (unspecified) alkyl group.

Group	CH₃?	C₂H₅?	CH₃CH₂CH₂?	(CH₃)₂CH?	CH₃CH₂CH₂CH₂?	(CH₃)₂CHCH₂?	CH₃CH₂CH(CH₃)?	(CH₃)₃C?	R?
Name	Methyl	Ethyl	Propyl	Isopropyl	Butyl	Isobutyl	sec-Butyl	tert-Butyl	Alkyl

IUPAC Rules for Alkane Nomenclature

1. Find and name the longest continuous carbon chain.
2. Identify and name groups attached to this chain.
3. Number the chain consecutively, starting at the end nearest a substituent group.
4. Designate the location of each substituent group by an appropriate number and name.
5. Assemble the name, listing groups in alphabetical order.
The prefixes di, tri, tetra etc., used to designate several groups of the same kind, are not considered when alphabetizing.

For the above isomers of hexane the IUPAC names are: B 2-methylpentane C 3-methylpentane D 2,2-dimethylbutane E 2,3-dimethylbutane

Halogen substituents are easily accomodated, using the names: fluoro (F-), chloro (Cl-), bromo (Br-) and iodo (I-). For example, (CH₃)₂CHCH₂CH₂Br would be named 1-bromo-3-methylbutane. If the halogen is bonded to a simple alkyl group an alternative "alkyl halide" name may be used. Thus, C₂H₅Cl may be named chloroethane (no locator number is needed for a two carbon chain) or ethyl chloride.

Cycloalkanes

Cycloalkanes have one or more rings of carbon atoms. The simplest examples of this class consist of a single, unsubstituted carbon ring, and these form a homologous series similar to the unbranched alkanes. The IUPAC names of the first five members of this series are given in the following table. The last (yellow shaded) column gives the general formula for a cycloalkane of any size. If a simple unbranched alkane is converted to a cycloalkane two hydrogen atoms, one from each end of the chain, must be lost. Hence the general formula for a cycloalkane composed of n carbons is C_nH_2n.

Examples of Simple Cycloalkanes
Name	Cyclopropane	Cyclobutane	Cyclopentane	Cyclohexane	Cycloheptane	Cycloalkane
Molecular Formula	C₃H₆	C₄H₈	C₅H₁₀	C₆H₁₂	C₇H₁₄	C_nH_2n
Structural Formula						(CH₂)_n
Line Formula

Substituted cycloalkanes are named in a fashion very similar to that used for naming branched alkanes. The chief difference in the rules and procedures occurs in the numbering system. Since all the carbons of a ring are equivalent (a ring has no ends like a chain does), the numbering starts at a substituted ring atom.

IUPAC Rules for Cycloalkane Nomenclature

1. For a monosubstituted cycloalkane the ring supplies the root name (table above) and the substituent group is named as usual. A location number is unnecessary.
2. If the alkyl sustituent is large and/or complex, the ring may be named as a substituent group on an alkane.
3. If two different substituents are present on the ring, they are listed in alphabetical order, and the first cited substituent is assigned to carbon #1. The numbering of ring carbons then continues in a direction (clockwise or counter-clockwise) that affords the second substituent the lower possible location number.
4. If several substituents are present on the ring, they are listed in alphabetical order. Location numbers are assigned to the substituents so that one of them is at carbon #1 and the other locations have the lowest possible numbers, counting in either a clockwise or counter-clockwise direction.
5. The name is assembled, listing groups in alphabetical order and giving each group (if there are two or more) a location number. The prefixes di, tri, tetra etc., used to designate several groups of the same kind, are not considered when alphabetizing.

Small rings, such as three and four membered rings, have significant angle strain resulting from the distortion of the sp³ carbon bond angles from the ideal 109.5º to 60º and 90º respectively. This angle strain often enhances the chemical reactivity of such compounds, leading to ring cleavage products. It is also important to recognize that, with the exception of cyclopropane, cycloalkyl rings are not planar (flat).

Hydrocarbons having more than one ring are common, and are referred to as bicyclic (two rings), tricyclic (three rings) and in general, polycyclic compounds. The molecular formulas of such compounds have H/C ratios that decrease with the number of rings. In general, for a hydrocarbon composed of n carbon atoms associated with m rings the formula is: C_nH_{(2n + 2 - 2m)}. The structural relationship of rings in a polycyclic compound can vary. They may be separate and independent, or they may share one or two common atoms. Some examples of these possible arrangements are shown in the following table.

Examples of Isomeric C₈H₁₄ Bicycloalkanes

Isolated Rings	Spiro Rings	Fused Rings	Bridged Rings
No common atoms	One common atom	One common bond	Two common atoms

elessar_iitkgp

Alkenes and Alkynes

Alkenes and alkynes are hydrocarbons which respectively have carbon-carbon double bond and carbon-carbon triple bond functional groups. The molecular formulas of these unsaturated hydrocarbons reflect the multiple bonding of the functional groups:

Alkane	R?CH₂?CH₂?R	C_nH_2n+2	This is the maximum H/C ratio for a given number of carbon atoms.
Alkene	R?CH=CH?R	C_nH_2n	Each double bond reduces the number of hydrogen atoms by 2.
Alkyne	R?C?C?R	C_nH_2n-2	Each triple bond reduces the number of hydrogen atoms by 4.

For example, consider compounds having the formula C₅H₈. The formula of the five-carbon alkane pentane is C₅H₁₂ so the difference in hydrogen content is 4. This difference suggests such compounds may have a triple bond, two double bonds, a ring plus a double bond, or two rings. Some examples are shown here, and there are at least fourteen others!

IUPAC Rules for Alkene and Cycloalkene Nomenclature

1. The ene suffix (ending) indicates an alkene or cycloalkene.
2. The longest chain chosen for the root name must include both carbon atoms of the double bond.
3. The root chain must be numbered from the end nearest a double bond carbon atom. If the double bond is in the center of the chain, the nearest substituent rule is used to determine the end where numbering starts.
4. The smaller of the two numbers designating the carbon atoms of the double bond is used as the double bond locator. If more than one double bond is present the compound is named as a diene, triene or equivalent prefix indicating the number of double bonds, and each double bond is assigned a locator number.
5. In cycloalkenes the double bond carbons are assigned ring locations #1 and #2. Which of the two is #1 may be determined by the nearest substituent rule.
6. Substituent groups containing double bonds are:
H₂C=CH? Vinyl group
H₂C=CH?CH₂? Allyl group

IUPAC Rules for Alkyne Nomenclature

1. The yne suffix (ending) indicates an alkyne or cycloalkyne.
2. The longest chain chosen for the root name must include both carbon atoms of the triple bond.
3. The root chain must be numbered from the end nearest a triple bond carbon atom. If the triple bond is in the center of the chain, the nearest substituent rule is used to determine the end where numbering starts.
4. The smaller of the two numbers designating the carbon atoms of the triple bond is used as the triple bond locator.
5. If several multiple bonds are present, each must be assigned a locator number. Double bonds precede triple bonds in the IUPAC name, but the chain is numbered from the end nearest a multiple bond, regardless of its nature.
6. Because the triple bond is linear, it can only be accomodated in rings larger than ten carbons. In simple cycloalkynes the triple bond carbons are assigned ring locations #1 and #2. Which of the two is #1 may be determined by the nearest substituent rule.
7. Substituent groups containing triple bonds are:
HC?C? Ethynyl group
HC?CH?CH₂? Propargyl group

Benzene Derivatives

The nomenclature of substituted benzene ring compounds is less systematic than that of the alkanes, alkenes and alkynes. A few mono-substituted compounds are named by using a group name as a prefix to "benzene", as shown by the combined names listed below. A majority of these compounds, however, are referred to by singular names that are unique. There is no simple alternative to memorization in mastering these names.

Two commonly encountered substituent groups that incorporate a benzene ring are phenyl, abbreviated Ph-, and benzyl, abbreviated Bn-. These are shown here with examples of their use. Be careful not to confuse a phenyl (pronounced fenyl) group with the compound phenol (pronounced feenol). A general and useful generic notation that complements the use of R- for an alkyl group is Ar- for an aryl group (any aromatic ring).

When more than one substituent is present on a benzene ring, the relative locations of the substituents must be designated by numbering the ring carbons or by some other notation. In the case of disubstituted benzenes, the prefixes ortho, meta & para are commonly used to indicate a 1,2- or 1,3- or 1,4- relationship respectively. In the following examples, the first row of compounds show this usage in red. Some disubstituted toluenes have singular names (e.g. xylene, cresol & toluidine) and their isomers are normally designated by the ortho, meta or para prefix. A few disubstituted benzenes have singular names given to specific isomers (e.g. salicylic acid & resorcinol). Finally, if there are three or more substituent groups, the ring is numbered in such a way as to assign the substituents the lowest possible numbers, as illustrated by the last row of examples. The substituents are listed alphabetically in the final name. If the substitution is symmetrical (third example from the left) the numbering corresponds to the alphabetical order.

Here are a few sites where you can learn nomenclature

http://www.chem.ucalgary.ca/courses/351/orgnom/index.html

http://www.acdlabs.com/iupac/nomenclature/

http://en.wikipedia.org/wiki/IUPAC_nomenclature_of_organic_chemistry

http://www.chem.qmul.ac.uk/iupac/

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