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Ask iit jee aieee pet cbse icse state board experts Expert Question: organic chemistry [admin]: why alkyl groups behave as electron donors ?
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ritu_007 (603)

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can you explain why alkyl groups behave as electron donors when attached to a  system?
 
I've repeated my question  because unfortunetly my question wasn't answered.so plzz.help me and answer this question as soon as possible.

"OUR GREATEST GLORY IS NOT IN NEVER FALLING.BUT IN RAISING EVERTIME WE FALL".
    
debajeet (-2)

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FOR +I EFFECT ALKYL GROUPS BEHAVES LIKE CARBO CATIONS.SO IT BEHAVES AS ELECTRON DONORS.
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lonelyguy (-2)

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ans:
double bonded carbon atom is using sp2 hybrised state so %s character increases therefore double bonded carbon atom is more electronegative than sp3 hybridised carbon thats why alkyl is showing +Ito double bonded corbon sys
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ac (222)

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Hi,
Your question has been answered.
Please see:
www.goiit.com/posts/list/769.htm

I would recommend you to read all types of electron displacements in organic compounds: Inductive Effect, Resonance and Hyperconjugation.



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arun-rashi (1131)

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any group which attrect electron less strongly than hydrogen have +I effect.due to very less electronegativity of sp3 carbon atom  these have +Ieffect.

Arun / Rashi - Authors Macromind MCQ of Chemistry from G.R Batla
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smartgoels (6)

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one factor responsible is hyperconjugation
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ritu_007 (603)

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thankyou .the solutions were of great help.

"OUR GREATEST GLORY IS NOT IN NEVER FALLING.BUT IN RAISING EVERTIME WE FALL".
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