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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: predic product..
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ramkumar_november (1270)

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predict the product....
 
3-bromo nitrobenzene when reacted with KCN at 420 degree celsius....
 
 

    
ashgirl (1434)

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is dat Br der??

Remember Cedric. Remember, if the time should come when you have to make a choice between what is right and what is easy, remember what happened to a boy who was good, and kind, and brave, because he strayed across the path of Lord Voldemort. Remember Cedric Diggory.


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ramkumar_november (1270)

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yes.

i have given the iupac name in my post..
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varshavallig (798)

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Br will be replaced by CN.3-cyano nitro benzene will be formed.
correct me if m wrong.
but i think this is what wil happen
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ananth_patri (590)

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ya may be Br is replaced by CN ??? Nu Subs???

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harsha_27 (1343)

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This reaction is a named reaction(I'm unable to remember right now) and is out of IIT syllabus......Here -COOH group is introduced.

PS: My msg may not answer your question.I'm saying this just for your information.





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dream (571)

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i also think that the ans shud be

2-cyano nitrobenzene
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ashgirl (1434)

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@ ramkumar_november, can u plz tell the answer??

Remember Cedric. Remember, if the time should come when you have to make a choice between what is right and what is easy, remember what happened to a boy who was good, and kind, and brave, because he strayed across the path of Lord Voldemort. Remember Cedric Diggory.


Albus Dumbledore
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sandeepramesh (1247)

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is it Von Richter rearrangement? I dont think it is right if it is meant to be so
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ramkumar_november (1270)

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this reaction is called von richter reaction.....
 
when halo-nitrobenzene is reacted with KCN at 420 C..... the nitro group leaves and the cyano group occupies the position ortho to nitro group.......
 
so the product is 1-cyano-2-bromo-benzene ....
 
here is the named reaction.....
 
 
von Richter Reaction.
 
 
 
 
 
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sandeepramesh (1247)

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EDIT: See my last msg
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ramkumar_november (1270)

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no no . the reaction takes place.......
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sandeepramesh (1247)

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EDIT: See my last msg
 
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ashish_banga (973)

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is it follows betyne mechanism
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sandeepramesh (1247)

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