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Forum Index -> Organic Chemistry like the article? email it to a friend.  
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dev_22oct (1326)

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compound A, C7H14 decolorises Br2 in CH2CL2 and reacts with BH3 in THF followed by H2O2/OH- to yield compound B. when treated with KMnO4, B is oxidised to a carboxylic acid C. compound A, after ozonolysis and work up with H2O2, yield the same compound D as formed by the oxidation of cyclohexanol with chromic acid. identify A,B,C,and D.
    
varshavallig (793)

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m not sure ,my ans:
A----- (dunno the name)---->cyclohexane==CH2
B---->cyclohexane-CH2-OH
c---->cyclohexane carboxylic acid
D--->cyclohexanone

plz correct me if m wrong
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tarinbansal (2432)

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Sir,
I think A shud be C7H12 not C7H14.
Anyways, I am attaching the structures of the compounds.


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dev_22oct (1326)

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yes u guys are correct.
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dev_22oct (1326)

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Q 3)compound A,C10H14O does not react with Br2 water , acetyl chloride or boiling NaOH solution . on reaction with excess of HI , A is converted into B, C3H7I and C, C7H7I . B can be hydrolysed by eq NaOH to D , C3H80 which gives iodoform test . C can be oxidised to carboxylic ,E,C7H6O2 by chromic acid .assign structures to A,B,C,D and E.
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tarinbansal (2432)

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Here's my shot-
 


The quality of a person's life is in direct proportion to their commitment to excellence, regardless of their chosen field of endeavor.

It is during our darkest moments that we must focus to see the light.

''Darr sabko lagta hai, Gala sabka sookhta hai
Par, darr ke aage hi jeet hai''
To mountain dew piyo and IIT mai jaao. :P

For those giving JEE in 2008-

http://www.goiit.com/posts/list/about-iits-how-many-of-u-are-giving-hav-given-jee-08-52658.htm
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dev_22oct (1326)

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good u r correct.
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