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18 Mar 2010 22:02:38 IST
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What are bicyclo compounds in nomenclature
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What are bicyclo compounds in nomenclature


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winx's Avatar

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19 Mar 2010 08:19:52 IST
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A class of saturated compounds consisting of two rings only, having two or more atoms in common, containing at least one hetero atom, and that take the name of an open chain hydrocarbon containing the same total number of atoms.

 

 

NOMENCLATURE  of bicyclic compounds

We name compounds containing 2 fused or bridged rings as bicyclo alkanes and we use the name of the alkane corresponding to the total number of carbon atoms as the base name. The carbon atoms common to both the rings are called bridgeheads, and each bond, or chain of atoms connecting the bridgehead atoms, is called a bridge.



In between the words bicyclo and alkane we interpose in the name an expression in the square brackets that denotes the number of carbon atoms in each bridge (in descending order). For example,



If substitutions are present, we number the bridged ring system beginning at one bridgehead, proceeding first along the longest bridge to the other bridgehead, then along the next longest bridge back to the first bridgehead. The shortest bridge in numbered last.

 

 

winx's Avatar

Scorching goIITian

Joined: 28 Jan 2010
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19 Mar 2010 08:25:16 IST
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more xamples wud b lyk dis

 

 


bicyclo[4.3.2]undecane

 


bicyclo[4.1.0]heptane

 


bicyclo[4.4.0]decane, aka decalin


7,7-dimethylbicyclo[2.2.1]heptane

 


4-ethyl-2-isopropylbicyclo[4.1.0]heptane

 



1,9-dimethylbicyclo[4.2.1]nonane

 


2,6,6-trimethylbicyclo[3.1.1]heptane

 

 

hope i helpd u...............

 

 

Sagar Saxena's Avatar

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Joined: 8 Oct 2008
Posts: 6343
19 Mar 2010 13:31:37 IST
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hii

A class of saturated compounds consisting of two rings only, having two or more atoms in common,

containing at least one hetero atom, and that take the name of an open chain hydrocarbon containing

the same total number of atoms.

 

in much simpler way

A bicyclic molecule is a molecule that features two fused rings. Bicyclic molecules occur in widely in organic and inorganic compounds.

Fusion of the rings can occur in three ways:

1. Across a bond between two atoms - for example, decalin (also known as bicyclo[]decane), has a C-C bond shared between two cyclohexane rings;
2. Across a sequence of atoms (bridgehead) - for example, norbornane (also known as bicyclo[]heptane), can be viewed as a pair of cyclopentane rings that share three of the five carbon atoms; or
3. At a single atom (spirocyclic, forming a spiro compound)

Singly fused rings are the most common, and spiro rings are the least common.

 

       !!!!!


Cool goIITian

Joined: 30 Mar 2008
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19 Mar 2010 20:06:56 IST
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Thank you very much for your kind reply




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