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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Which of the following compound show optical isomerism?
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payal1spark (0)

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Which of the following compound show optical isomerism?


cis-[Co(NH3)4Cl2]+

(ii) trans-[Co(en)2Cl2]+

(iii) cis-[Co(en)2Cl2]+

(iv) [Co(en)3]3+

plz expln

    
tarinbansal (3903)

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The answer is 3,4.

Just draw the structural formula and then draw its mirror image and try to superimpose the 2 compounds. If they superimpose, they are OPTICALLY INACTIVE.
If they dont superimpose, they are OPTICALLY ACTIVE.

Out of these 4 compounds, only 3,4's images were non superimposable.
If U dont get it, tell me. I will draw their figures.

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can u manage to draw the figures?...i know thts a trouble for u....if u cant its completely okk..
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tarinbansal (3903)

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I am posting the figures of optically active compounds only.


As far as compound (ii) is concerned, u can draw it by seeing compound (iii). Just replace the position of one en and Cl. U will find ki its symmetrical and hence optically inactive.


I think (i) is also optically active. Not much sure. Lemme see it again. Will tell you if it is also optically active.



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tarinbansal (3903)

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No, (i) is not optically active.




 


 


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