sign up I login
 advanced
refer a friend - earn nickels!!

Ask & Discuss Questions with Community & Experts

Moderation Team
 90 chars left    advanced
Ask iit jee aieee pet cbse icse state board experts Expert Question: Why is zinc preferred over any other element to form an alkene with vic dyhalide ??
Forum Index -> Organic Chemistry like the article? email it to a friend.  
Author Message
helloo (0)

New kid on the Block

Olaaa!! Perrrfect answer. 0  [0 rates]

helloo's Avatar

total posts: 3    
offline Offline
Why is zinc preferred over any other element to form an alkene with vic dyhalide ??
    
madhusudan.chavan (976)

Forum Expert Blazing goIITian

Olaaa!! Perrrfect answer. 166  [239 rates]

madhusudan.chavan's Avatar

total posts: 614    
offline Offline

Zinc is comparatively an inert element hence is preferred over other metals for dehalogenation of vicinal dihalides. With sodium the dihalide undergoes Wurtz reaction. With zinc the dehalogenation occurs by E2 mechanism. Lone pair of electron on zinc attacks one of the bromine atom , forms a partial bond at the same time C-Br bond is breaking and formin carbon carbon double bond. This transition state the gives alkene.


Other means of removing bromine atoms are sodium iodide or chromous chloride or chromous sulphate or sodium trimethoxy borohydride.

 this reply: 2 points  (with Olaaa!! Perrrfect answer.   in 1 votes )   [?]
 
You have to be logged on to rate
  
 
Forum Index -> Organic Chemistry
Go to:   

Top Offers for goIITians
Correspondence Courses
Brilliant Tutorials
Narayana Institute
Aakash Institute
Classroom/Crash Courses
Narayana - Kota , Delhi , Others
Brilliant Tutorials - Class , Crash
Aakash Institute - Medical , Engg
Online Test Series
Brilliant Tutorials
Narayana Institute
Aakash Institute
Mahesh Tutorials
AMITY      Sri Chaitanya