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Organic Chemistry

Cool goIITian

Joined: 2 Oct 2009
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11 Oct 2009 13:00:32 IST
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wts decarboxylation reaction?plz tell.....rates assured........
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wts decarboxylation reaction?plz tell.....rates assured........


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djdylan2000. bits goa eee's Avatar

Blazing goIITian

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11 Oct 2009 13:13:28 IST
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RCOOH-------------------> R-H + CO2

(heated, in the presence of sodalime (NaOH+CaO) 

Vijay Pal's Avatar

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Joined: 1 Jun 2009
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11 Oct 2009 13:28:56 IST
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Hello dear

 

Sodium salts of corboxylic acids on heating with soda lime (mixture of sodium hydroxide and calcium oxide) give

 

alkanes containing one carbon atom less than the corboxylic acid.This process of elimanation of carbon dioxide

 

from corboxylic acid is known as decorboxylation.

 

CH3 COO-Na+ +NaOH ---------------------> CH4 +Na2 CO3

 

 


New kid on the Block

Joined: 6 Oct 2009
Posts: 14
11 Oct 2009 13:35:03 IST
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decarboxylation means the removal of -COOH group from the compound or somply the removal of CO2

there r various reagents which makes the reaction to proceed towards decarboxylation such as

CaO,through electrolysis,HI in presence of P at about 500k,etc

Vivek  Roy's Avatar

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12 Oct 2009 11:33:44 IST
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Decarboxylation is the removal of the COOH group from a compound on strongly heating it. It doesn't have to be the sodium salt...........



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