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Ask iit jee aieee pet cbse icse state board experts Expert Question: BaO2 is peroxide but MnO2 s dioxide-why?
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sreemoyee07 (0)

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BaO2 is peroxide but MnO2 s dioxide-why?

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svj29 (2196)

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dude in BaO2 the oxidation state of O is -1 and in MnO2 it is -2.

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konichiwa2x (2373)

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stability of peroxides and superoxides increases with increase in atomic somic. Ba2+ is much larger in size than Mn2+ and hence it readily forms peoxide.

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krishna.gopal (2697)

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How can you compare BaO2 with MnO2. BaO2 belongs to second group and has an oxidation state of +2. So oxygen has oxidation state of -1 and hence BaO2 is peroxide.
Mn is a trasition metal and in MnO2 its oxidation state is +4 and that of Oxygen is -2 So its a normal oxide

Krishna Gopal Singh
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IIT Delhi 2002
Currently doing PhD from IIT Delhi
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