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Physical Chemistry
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The formula for bond order is calculated using the formula (nb-na)/2
nb- total electrons in bonding orbitals
na- total electrons in anti bonding orbitals.
step one.
Draw the molecular orbital configuration for both the molecules.
count the number of electrons in bonding and antibonding orbitals
apply the formula given above.
The Molecular orbital configuration of CO2 is follows
Bonding Orbitals- MO1 ,MO4,MO5,MO7
ANTIBONDING ORBITAL -MO2, 3 ,6,8
NON BONDING ORBITALS- MO 9 ,10,11,12
NO OF ELECTRONS =16
NO OF ELECTRONS IN BODING ORBITALS = 8
nO OF ELECTRONS IN ANTIBONDING ORBITALS= 0
NO OF ELECTRONS IN NON BONDING ORBITALS= 8
BOND ORDER = 8/2 = 4 AS THERE ARE TWO OXYGEN ATOMS THE BOND ORDER OF ONE C=O IS 4/2=2














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