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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: charge on radicals
Forum Index -> Physical Chemistry like the article? email it to a friend.  
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tarun_bits (639)

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hey..i m facing a foolish delima
 
why OH- has negative charge...

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comshubham (76)

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only trust if i m right..........
valency of O= -2
valency of H= +1

hence when O & H combines need of one electron is fulfilled while another one is not.
So, OH haves a -ve charge
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tarun_bits (639)

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oh...now its there,,i think that -1 represents the valency of OH-

<TABLE CELLSPACING="1" CELLPADDING="1" BORDER="0">
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master_purav (1341)

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-1 indicates that there is one excess pair of electrons in the radical.


"If you win, you shall not have to explain and if you lose, you wont be there to explain"
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tarun_bits (639)

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draw the structure of the molecule
 

<TABLE CELLSPACING="1" CELLPADDING="1" BORDER="0">
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tarun_bits (639)

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both of u have different answers
 

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karthik2007 (3355)

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Calculate the formal charge on each atom.. and add!

Will nip in at times to solve problems :)
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kane (2179)

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yaar oxygen ka oxidation state is -2 and that of hydrogen is +1.therefore OH has -1 charge.tabhi toh it combines with metals like K,Ca as KOH and Ca(OH)2
as K and Ca have +1 and +2 oxidation state resp.chemical compounds always have 0 oxidation state.

there are numerous options besides I.I.T

<TABLE CELLSPACING="1" CELLPADDING="1" BORDER="0">
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tarinbansal (3691)

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Well tarun,
U said that -1 is valency of OH. I think it would be better not use the word VALENCY as it is best defined for elements is atomic state.
Karthik2007,
Formal charge is the charge on atoms OR molecules of the compound which forms crystal lattice. eg-NaCl. We can't define formal charge for O and H in OH- .
OH has 1 -ve charge simply denotes that it is an anion which is unstable and can combine with cations to form compounds.

Hope its clear now.

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