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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 19:15:07 IST
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which of the following has the highest dipole moment:
CH3Cl
CHCl3
CH2Cl2
CCl4
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 19:17:51 IST
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i think it will b chcl3 and then chcl3 and then ch2cl2 and then ccl4
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 19:19:50 IST
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Well JOSHI even i opted for chcl3 but it is not the correct ans.
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:17:16 IST
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yes friends it shud be ccl4 the reason is that it is not a linear molecule its a 3-d tetrahedral shape .
in all the 4 compounds carbon atomis sp3 hybridised meaning they are all tetrahedral in shape so more the number of electron withdrawing groups higher the dipole moment .
hope u get it . allways remember this fact that u cant visualize the molecule to be planar . its 3 dimensonal .
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:25:10 IST
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chemical bonding
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:26:45 IST
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yes its CH2Cl2 i guess
CCl4 has 0 dipole moment
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:26:52 IST
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All the above compounds are tetrahedral in shape. Since the dipole moment of a bond is aligned parallel to that bond, we have a tetrahedron of dipoles.
If all the dipoles are equal, they will cancel out if arranged tetrahedrally, that happens in CCl4, it has a 0 dipole moment.
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:28:31 IST
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its chcl3
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 22:29:54 IST
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plz rate me if i m correct...thanks
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 12 May 2008 23:10:17 IST
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@ X4, dude ya have confused dipole moment with bond moment.
Dipole moment is a vector quantity and if any molecule has tetrahedral shape and all four atoms attached are same, then there will be high bond moment, but 0 dipole moment.
as per the answer is concerned it is CH2Cl2...
i tried to configure out the reason, but ended up with the conclusion that, this is an exception. even if you'll get a answer to this question, the concept can't be applied on other questions.
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 13 May 2008 01:43:16 IST
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ANS IS A
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 13 May 2008 01:45:47 IST
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BECAUSE IN OTHER ATOM MORE NO. OF CL ATOM MEANS CORBON POSITIVE CHARGE IS SHARE WITH MORE CL ATOM THAN DIPOLE MOMEN DECREASE
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 13 May 2008 01:49:18 IST
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its CH2Cl2
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 3 Jul 2008 22:35:33 IST
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chcl3 ccl4 has zero dipole
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 3 Jul 2008 22:40:38 IST
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Similar to
http://www.goiit.com/posts/list/organic-chemistry-among-i-ch3cl-ii-chcl3-which-molecule-has-69609.htm
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