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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: electrochem
Forum Index -> Physical Chemistry like the article? email it to a friend.  
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jatinpreet (12)

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How to solve this type of question?
 
The oxidant(s) whose oxidizing power is affected with the change in pH is/are ?
 
A] I2
B] Cr2O4-
C] MnO4-
D] NO3-
 

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jatinpreet (12)

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no replies yet

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jatinpreet (12)

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Still waiting !!!!!!!!!!!!!!!!!!!!

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debajeet (-2)

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THE ANSWER IS IODINE.
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jatinpreet (12)

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How? can U explain a little .........

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rahul_c (188)

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answer to the question is IODINE
              Cr2O4-  OXIDATION STATE  OF Cr=+3
               MnO4-  OXIDATION STATE  OF Mn=+7
            NO3-  OXIDATION STATE  OF N=+5
 
NOW THE ABOVE ELEMENTS CAN GET REDUCED (accept electrons to reach their normal configuration)
AS THEY ARE AT MAXIMUM OXIDATION STATE
  
           OXIDATION STATE  OF I2=0 ( I2 is iodine)
     I2 CAN GAIN 2 ELECTRONS TO FORM 2I-   , .PRESENCE  OF I- IN THE   SOLUTION INTERFERES WITH THE H[+] CONCENTRATION THEREBY BRINGING A CHANGE IN pH

The yardstick of human intelligence is the ability to overcome the last fallacy
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jatinpreet (12)

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Thanks alot . U deserve a salute.

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smartgoels (6)

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well sorry as far as chromium is being concerned its max oxidation state is 6
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rahul_c (188)

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smartgoels
  i accept that +6 is the highest o.n for Cr.But for Cr to bring a change in pH you would require a very good oxidising agent to reach from +3 to+6.In presence
H[+] that cannot be achieved

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