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Physical Chemistry
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Akhil
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Joined: 17 Jan 2008
Posts: 1451
1 Mar 2008 11:16:54 IST
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SHE is fixed relative to hydrogen....it is assumed to be zero and others are calculated relative to it
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1 Mar 2008 22:02:07 IST
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electrode potential values are relative. Its possible to calculate nd measure only the differnce in potential between two cells, its not possible to calculate the absolute potential of a half cell. Hence, an electrode has to be fixed as reference electrode relative to which other potentials are defined, whch is hydrogen electrode whose potential, by convention, is zero











