Physical Chemistry

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Explain the mechanism of nitartion of nitro benzene.
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Explain the mechanism of nitartion of nitro benzene.



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Sagar Saxena's Avatar

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Joined: 8 Oct 2008
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16 Jul 2012 18:04:34 IST
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 HELLO.......

step 1.

an acid/base reaction ...protonation of the hydroxyl group of nitric acid...this provides a better laving group.....

step 2.

loss of the leaving group ,a water molecule provides the nitronium ion .......

step 3.

the electrophilic nitrinium ion react with the nucleophilic c=c of the arene........this is the rate determiig step....

step 4.

water function as a base to remove the proton from the sp3 c baering the nitro group and eform the c=c ant the aromatic system..

 




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