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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Kinetics
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golu1234 (0)

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A substance decomposes according to second order


rate law.If the rate constant is                              


6.8 x 10-4   /mole/s,Calculate half - life of the


substance if the initial concentration is 0.05 mole/L.

    
golu1234 (0)

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In my opinion no one can solve this question

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rhd92781 (631)

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half life, t1/2=1/ka .........for a second order reaction


put the values, t1/2=29412 sec


<TABLE CELLSPACING="1" CELLPADDING="1" BORDER="0">
<TR><TD>


<DIV ALIGN="right">Animated Letters</DIV></TD></TR></TABLE>

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ssbrightstar1 (5)

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but for second order


 


t i/2 = 1/k.a.n


 


But u haven't put the value of n

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rhd92781 (631)

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formula for T1/2 for nth order reaction (n>=2) is


T1/2= (2n-1 - 1) / (n-1)kn(a)n-1


put the value of n here, n=2.


just apply the simple approach, -dA/dt = kAn and integrate it.


<TABLE CELLSPACING="1" CELLPADDING="1" BORDER="0">
<TR><TD>


<DIV ALIGN="right">Animated Letters</DIV></TD></TR></TABLE>

I am only one,
But still I am one.
I cannot do everything,
But still I can do something;
And because I cannot do everything
I will not refuse to do the something that I can do.
- Edward Everett Hale
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