Physical Chemistry

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:13:35 IST
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most difficult problem of redox reactions........!
Engineering Entrance , Medical Entrance , AIPMT , JEE Main , AIIMS , JEE Advanced , Chemistry , Physical Chemistry

 this is one of the hardest redox equation. so, if you can do this , you can do any kind of problem in chemistry.

 
the problem is 
 
CuSCN+KIO3+HCl === CuSO4+KCl+HCN+ICI+H2O
(BALANCING REDOX EQUATION)
 
ACID OR BASES IT'S DOES NOT MATTER



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Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:22:52 IST
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4 CuSCN + 10 HCl + 7 KIO3 = 4 CuSO4 + 7 ICl + 4 KCN + 5 H2O + 3 KCl

Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:24:16 IST
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dis wasn't tough !!!!!!!!!!

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:24:41 IST
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no thats not the correct ans

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:25:56 IST
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kareena are u on facebook

Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:27:44 IST
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BUT EVERYTHING IS CORRECTLY BALANCED ...............

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:28:33 IST
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are you absolutely sure of the formula & zero charge on CuSCN... if so, the Cu+1 ---> Cu+2 & 1 electron lost======================SCN- half reaction is given as #13 @http://books.google.com/books?id=SNzXKVC?SCN- --> SO4-2 & HCN- & 6 electrons lostplus the: Cu+1 ---> Cu+2 & 1 electron lostgives:so CuSCN --> CuSO4 & HCN & 7 electrons lost======================================?KIO3 & 4 e- taken --> I+1 (that's the iodine in ICl)=====================the ratio to balance the electrons should be 4:7....================4CuSCN --> 4CuSO4 & 4HCN 7KIO3 --> 7KCl & 7ICl=======================4CuSCN & 7KIO3 & HCl --> 4CuSO4 &7KCl & 4HCN & 7 ICl & H2Obalance the Cl's & the H+'s4CuSCN & 7KIO3 & 14 HCl --> 4CuSO4 & 7KCl & 4HCN & 7 ICl & 5 H2Oshould be done

Blazing goIITian

Joined: 19 Mar 2012
Posts: 421
31 May 2012 21:28:37 IST
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no m not on facebook ........

Cool goIITian

Joined: 17 Apr 2012
Posts: 34
31 May 2012 21:29:36 IST
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this is right

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:30:18 IST
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can u give me ur contact no

Blazing goIITian

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31 May 2012 21:32:03 IST
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why do u need it

Cool goIITian

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31 May 2012 21:33:13 IST
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ya

Cool goIITian

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31 May 2012 21:34:34 IST
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u r in which class n whts ur age

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:36:35 IST
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reply please

Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:36:44 IST
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m in class 10

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:39:02 IST
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give ur contact no

Cool goIITian

Joined: 17 Apr 2012
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31 May 2012 21:39:24 IST
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we can be friends

Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:41:20 IST
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no need of contact no. we can b friends without it....so friends ???????

Cool goIITian

Joined: 17 Apr 2012
Posts: 34
31 May 2012 21:41:58 IST
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ya bt how..??

Blazing goIITian

Joined: 19 Mar 2012
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31 May 2012 21:44:53 IST
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just friends on goiit............afterall our aim is to clear iit not 2 make friends...........



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