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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Simple assertion reason....
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Ronaldooo (44)

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Assertion-HF is a weak acid,but its strength inc. with inc. in concentration of acid.
Reason-F- reacts with HF to form HF2- thereby shifting ionization of H-F to the right.
Plzz help.

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Ronaldooo (44)

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Isnt anyone interested in helping people like me????

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Ronaldooo (44)

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Anyone!!!!!!!????????

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iitjee08aspirant (284)

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if im not wrong doesnt it form a dimer??? that is H2F2
in that case ans shud be that assertion is wrong but reason is wrong

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hash_include (381)

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Ans: assertion & reason r rite and reason is correct explanation.

the unionised F- reacts wid the HF.. this forms HF2- (as stated in the qsn)

and due to le-chatelier's principle, the equilibrium for the reaction

                      HF    H+  + F-

is shifted to the right as F- is getting depleted.

and hence, HF will furnish more H+ ions, thus increasing the acidity
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Ronaldooo (44)

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Ok agreed the reason is correct,but dont you think the assertion is wrong.
Because for weak acids,degree of dissociation=root(Ka/C)
Thus,if conc. is increased,dissociation will decrease and hence its strength should decrease.But,its given that it increases.Am i wrong somewhere???

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