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ashgirl (1434)

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1.   if the edge lenght of unit cell of NaCl is 600pm and ionic radius of Cl ion is 190pm, then the ionic radius of Na ion is:
i. 310
ii. 110
iii. 220
iv. none
 
2.in a solid AB having NaCl structure 'A' atoms occupy the  corners of unit cell. if all the face centered atoms along one of the axes are removed, then resultant stoichiometry is:
AB2
A2B
A4B3
A3B4
 
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ashgirl (1434)

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c'mon guys( and gals). it is urgent!!!!!!

Remember Cedric. Remember, if the time should come when you have to make a choice between what is right and what is easy, remember what happened to a boy who was good, and kind, and brave, because he strayed across the path of Lord Voldemort. Remember Cedric Diggory.


Albus Dumbledore
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chimanshu_007 (11437)

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ans 1) 110 pm
 
edgelength = 2 (radius of cation + radius of anion)

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lokeshsardana (685)

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NaCl is fcc type structure so,sqrt(2). edge length= 2(radius of cation + radius of anion)

LOKESH SARDANA,
department of Production and Industrial engineering,
Indian Institute of Technology,Roorkee.


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chimanshu_007 (11437)

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ans 2) 6 face centres are there so that means 6A atoms

removing FC atoms frm one of the AXES means removing 2A atoms

now. no of A atoms = 8 x 1/8 (corner) + 4 x 1/2 (face centred)

= 3

no. of B atoms/unit cell

12 x 1/4 (edge centred) + 1 (body centred) = 4

so resultant stoch. = A3b4

I always like to walk in rain as no one can see me crying there :(
frnds are like diamonds , if u hit them , they don't break but they slip frm ur hands
-----It is better to be hated for what you are than to be loved for what you are not.----
*****wen love and skill work together--expect a masterpiece*****






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lokeshsardana (685)

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sooooooorrrrrrrry, my mistake, himanshu is right........

LOKESH SARDANA,
department of Production and Industrial engineering,
Indian Institute of Technology,Roorkee.


Happiness can be found, even in the darkest of times, if one only remembers to turn on the light.
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Harry Potter and the Prisoner of Azkaban movie


There are only two ways to live your life. One is as though nothing is a miracle. The other is as though everything is a miracle.
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