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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: solid state problem..
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joyfrancis (1504)

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A crystal lattice comprising A and B has NaCl structure, with A on each of the corners , B lying on any one of the axis are removed..find the formula of the lattice.

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ashish_banga (927)

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A4B15
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rishipratimm (473)

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can u pls xplain wot is meant by axis in d q???

"Many of the things you can count,dont count....
Many of the things you cant count,really do count...."-Albert Einstein

"The important thing in science is not so much to obtain new facts as to discover new ways of thinking about them"-William Bragg

"An inexplicable fact is infinitely preferable to an incomprehensible mystery"-F. Soddy


RISHIPRATIM MAZUMDAR
NIT DURGAPUR
1ST YEAR,ELECTRONICS AND COMMUNICATIONS
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aditi_g (355)

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its gonna be A3B2
see.... total A and B atoms are gonna be 4 each...contributn of each axis 4/3...B left 4 - 4/3 = 8/3
so now the new formula is A12 B 8 ie A3B2....
i suppose u meant B to be removed...ITs not very clear in the ques so i just assumed it
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nakul2891 (0)

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AB2 i think


A=1/8 X 8

B=1/2 X 4 [2 are removed]

Am i right pls any one repy
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dream (569)

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well see the co ordination no in NaCl structure is 4:4
when u remove one atom say B, the co ordination no ratio becomes 4:3

so i think the answer is A4B3
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nakul2891 (0)

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No the correct answer is A3B4...because in rock salt the corner particles also occupy the face centre....

Its an IIT 2001 question..
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