Physical Chemistry

Blazing goIITian

Joined: 10 Oct 2011
Post: 431
17 May 2012 21:55:55 IST
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the volme in ml of 0.05 M KMnO4(acidic) required to oxidize 2 gm of FeSO4 in dilute solution is
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the volume in ml of 0.05 M KMnO4(acidic) required to oxidize 2 gm of FeSO4 in dilute solution is



Comments (4)


Hot goIITian

Joined: 29 Mar 2012
Posts: 158
17 May 2012 22:24:00 IST
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is ans 52.63 ml ?


Blazing goIITian

Joined: 10 Oct 2011
Posts: 431
17 May 2012 23:06:14 IST
0 people liked this

yes...but how?

Blazing goIITian

Joined: 10 Oct 2011
Posts: 431
17 May 2012 23:06:14 IST
0 people liked this

yes...but how?

Hot goIITian

Joined: 29 Mar 2012
Posts: 158
18 May 2012 00:23:59 IST
1 people liked this

KMnO4 + 5FeSO4 ==== 5 FE3+ + Mn2+

oxidation no. of Mn changes frm +7 to +2  gain of 5e-

therefore 5 Fe reacts with KMnO4 so that Fe2+ changes to Fe3+

e- loss  == e- gain

therefore 1 mol  requires 5 mol of Fe2+

so ? many moles of KMno4 shud react with 2/152 mols of Fe  (mol wt of FeSO4 is 152)

it cums out 2 b 2.63 milli moles

derfore 0.05 * vol = 2.63 mili mols

so vol is 52.6 ml

 




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