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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: Try this equilibrium question!!!
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sachin_gupta1991 (69)

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Q. A mixture of SOand O2 at 1 atm in the mole ratio of 2:1 is passed thru a catalyst at 1170 (degree celsius) at a rate sufficient for the attainment of equilibrium.The existing gas,suddenly chilled and analysed , is found to contain 87% SO3 by volume.                          
Calculate kp for the reaction:  SO2+ O2  (reversible rxn.)   SO3.     
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vishesh_saxena1 (177)

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Is the answer 2455.4
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shubham_sachdeva (1901)

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look,

let the initial concentrations of so2 & o2 be 2 & 1 litre....

& let us assume that x litre of o2 gets used up for attaining equi..

so final volumes will be:-


(2-2x) +(1-x) + (2x) = 3-x

now we r given 87% so we get

2x/3-x * 100= 87/100

calculate x from above....then its easy man.....calculate pressure & hence Kp.

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