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Forum Index -> Physical Chemistry like the article? email it to a friend.  
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sampan (10)

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If the radius of the 1st Bohr orbit in a hydrogen atom can be determined  with an uncertainity of 1% .What will be the minimum velocity of electron in that orbit ?
 
 Answer to the problem is 1.09*(10 power 8)m/s
 
please help as i cannot make anything out of the problem!
 

sampan ganguly
    
rahul_c (188)

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RADIUS OF THE FIRST BOHR ORBIT IS 0.53 ANGSTROM =0.53*(10^(-10))
 
BY HEISENBERG'S UNCERTAINITY PROBLEM WE KNOW THAT
 
  p*x >= h/(4(pie))--------(1)
 
  where p= momentum of the electron
        x= uncertainity in the location of Bohr orbit (1%= 10^(-2))
        h= planck's constant (6.62 * 10^(-34)) Js
 
 p can be expressed as m*v
        where m = mass of the electron ( m=9.1*10^(-31)kg)
              v= velocity of the electron
  putting the values in (1) we get  pie=3.14
 
v >=6.62*10^(-34)/[(4* 3.14)*9.1*10^(-31)*0.53*(10^-10)*10^(-2)]  

v >= 1.094 * (10^8) m/s
therefore the least value of velocity is 1.094 * (10^8) m/s  
 
with regards                                

The yardstick of human intelligence is the ability to overcome the last fallacy
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sampan (10)

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o thanks a lot. i completely forgot heisenberg's priciple

sampan ganguly
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smriti.mathur (437)

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The problem is based on Heisenberg's Uncertainty Principle which state that 'it is not possible to determine simultaneously both the position and momentum of an electron'. It is given by the formula-
p  *x  =h /4pie
where, p = momentum of the electron (mass of electron * velocity)
           x = uncertainty
            h= planck's constant
By putting the values, the velocity of the electron can be calculated.

Lecturar, Organic Chemistry
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