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11 Feb 2009 17:38:36 IST
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why 4 covalent bonds cnnt be frmd between 2 carbon atoms????(to satisfy valency of carbon)
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why 4 covalent bonds cnnt be frmd between 2 carbon atoms????(to satisfy valency of carbon)


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Bhaskar Tetarbe's Avatar

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Joined: 15 Jul 2007
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12 Feb 2009 10:03:13 IST
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We know C has 1s,2s and one 2p. A pi bond involves either p or d orbital. The 2nd and 3rd bond makes for 2 pi bonds involving one 2p orbital. Since, s-orbitals can't form pi bonds, therefore 4 covalent bonds cannot be formed between 2 carbon atoms.

New kid on the Block

Joined: 11 Feb 2009
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12 Feb 2009 21:34:37 IST
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but 2p cn accomodate 6 electrons so 3 pi bnds are possible through p orbiltals..............n the left 1 sigma bond cn be frmed using 2s orbital.
10904him's Avatar

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Joined: 29 Dec 2006
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12 Feb 2009 21:38:17 IST
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No confusions -------Obviously you require space to form a fourth bondThere is electron cloud on all sides of a triple bond and so you cant adjust another bond.Further the p-z orbitals are oriented away from both c-atoms and cannot form a bond.

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Joined: 9 Oct 2008
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13 Feb 2009 09:40:03 IST
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'Bhaskar' is absolutely right.



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