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Thermal Physics
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26 Jul 2009 15:58:30 IST
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Cp / Cv = Gamma = N + 2 / N where N = 3A - R, where further A = number of molecules and R = number of bonds.
For monoatomic, N = 3 and so Gamma = 5/3. For diatomic, N = 5 and Gamma = 7/5 and so on. To calculate values of Cp and Cv separately, use Mayer's relation i.e. Cp - Cv = R.













Use this other known eqn dude:
Cp=Cv+R
So γ=Cp/Cv
Cp=Cv+R= 5R/2+R=7R/2
Cv= 5R/2.
therefore, γ=7/5