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Catalogs Discussion Forums -> Physical Chemistry -> bond angle -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Remeber that a few bond angles can be calculated by the formula --
@ = cos(inverse)(1/p) where p indicates the no of p orbitals taking part in the hybridization.
Catalogs Discussion Forums -> Electricity -> Charges -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
If charges on them are widely different--
Yes they will attract each other because the charge on one is much much larger than the smaller charge thus if they are brought closer then due to induction -ve charge comes up and attraction occurs.
But if you say there is only size difference it seems a bit awkward.
Catalogs Discussion Forums -> Organic Chemistry -> organic killer pls -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
H2O2 can be used as both an oxidizing as well as a reducing agent and in most organic reactions the H2O2 plays the role of organic peroxide.Ir forms free radicals as 2OH*.
On the other hand HBr is mainly the reagent tsking part in ene / ynes
It gives free rad in hv and also gives addition reactions.
Catalogs Discussion Forums -> Physical Chemistry -> bong angle -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
bond angle @ = cos(inverse) (1/p) where p represents the no of p orbitals engaged in hybridization
Mostly the values are true if the dipole moments are not affecting.
Ex---sp ----cos(inverse) (1) =180
sp2 ------cos(inverse)(1/2) = 60
sp3-------cos(inverse)(1/3) =109.47 etc.
Catalogs Discussion Forums -> Mechanics -> pls explain........its easy -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
When they form a square then both diagonals are equal
B(x,y)
D(x,-y)
A(0,0)
C(2x,0)
l =( x^2 + y^2)^1/2
Differentiating dt
0 = 1/2(2x dx/dt + 2y dy/dt)
---------------------------
( x^2 + y^2)^1/2
2x dx/dt + 2y dy/dt = 0
When they form a square
x= l /(-/2)
y= l /(-/2)
dx / dt =v
dy / dt =-dx / dt =v (d) Ans
Catalogs Discussion Forums -> Physical Chemistry -> Molarity & Molality -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
For molality ---
100 ml of each sol
--> 121.8 gm 30% sol ----121.8 X 70/100 =85.3 gm solvent and 121.8 - 85.3 gm solute =36.5 gm solute = 0.37 mol acid

Similarly

---> 161 gm 70% sol ----161 X 30/100=48.3gm solvent and
161-48.3 =112.7 gm acid =1.15 mol acid
Thus on mixing 100 ml of each solution of 200 ml forms with
1.15 +0.37 =1.52 mol acid

Total mass of solvent = 85.3 + 48.3=133.6 gm

Molality =1.52 / 0.1336 = 11.4 m Ans
Catalogs Discussion Forums -> Physical Chemistry -> Molarity & Molality -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
30 % acid d=1.218
30 gm acid ------ 100 gm solution------70 gm solvent
30/98 mol=0.31 mol acid ---100 gm sol
0.31 mol acid in 100/1.218 ml =82.1 ml solution
M1=0.31 x1000/82.1 = 3.8 M

Similarly-

70 % acid d=1.61
70 gm acid ------ 100 gm solution-------30 gm solvent
70/98 mol=0.71 mol acid ---100 gm sol
0.71 mol acid in 100/1.218 ml =62.1 ml solution
M2 =0.71 x 1000/62.1 =11.4 M
Molarity of Mixture =M1V + M2V / 2V = (M1 +M2 )/ 2
=11.4+3.8/2 = 7.6 M ans
Catalogs Discussion Forums -> Physical Chemistry -> Molarity & Molality -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
1- Mol Wt. =158
100 gm sol ----5 gm solute
100 gm sol----5/158 mol =0.032 mol of solute
Mass of solvent = 100 -5= 95 gm
Molality=0.032/0.095 = 0.34 m Ans

Vol of soln = 100/1.04=96.2 ml
Molarity = 0.032/0.0962 = 0.33 M Ans

Mol of water = 95/18 =5.3 mol
Mol of solute = 0.032
Mol Fraction = 0.032 / 5.332 = 6 x 10 ^-3 Ans
Catalogs Discussion Forums -> Organic Chemistry -> can anyone give a detail solution to this organic question -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
I think the third one is the most basic
Catalogs Discussion Forums -> Trignometry -> A good (according to me) question -> Go to message
This Post 10 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]
since cot( ) is 1 or more than 1 thus here it should be exactly one in this case because elsewise the product cannot be 1
Thus A1=A2=A3=...................An=45
cos(45) = 1/ -/ 2
Thus the product = (1/ -/ 2 )^n Ans
Catalogs Discussion Forums -> Mechanics -> differentiate between: -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Have you ever come across a question based on decreasing acceleration Buddy Guy but you may have come across many questions on decelaration where acc was constant.I think what you say is wrong.
Catalogs Discussion Forums -> Mechanics -> HC VERMA KINEMATICS Q -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
6 particles are located at the 6 corners of a regular hexagon of side a. If each moves with a constant velocity of v always towards the particle at the next corner then find the time taken for the particles to meet.                 (ANS= 2a/v)
 
 
Answer first and get the salute.
Catalogs Discussion Forums -> Organic Chemistry -> organic -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
I think the answer should be (A) because HCl(gas) will evolve out but HBr being a liquid remains in the solution and decomposes on heating.
Actually I am not sure enough yet.
Catalogs Discussion Forums -> Organic Chemistry -> finding acidity of compounds -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
1-Check for the inductive effects if any . Any-I group will increase the strength of the acid.

2-Check whether the acid after losing its hydrogen ion is stable.More stable its anion the more strong will be the acid.

3-If the molecule of the acid is more stable then it will have lesser tendancy to lose the H+ ion.

4-Remember that the +I groups will decrease the acid strength.
Catalogs Discussion Forums -> Analytical Geometry -> BINOMIAL -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Short Cut Trick----

C0 Cr + C1Cr+1+ ............... ........... = (2n)!
-------------------
(n-r)! X (n+r)!
Catalogs Discussion Forums -> Organic Chemistry -> nomenclature -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Thank You Ma'am that was an excellent experience for me to talk to you.
Thank You once again.
Catalogs Discussion Forums -> Mechanics -> mechanics -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
I read somwhere that such assumptions are made in honour of the ancient scientists and their works
Also for simplicity as most of the cases considered all on the earth
Catalogs Discussion Forums -> Organic Chemistry -> challenging NOMENCLATURE -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
SORRY THE FORMATTING IS WRONG

Monovalent      Divalent         Trivalent         Tetravalent etc.
-yl                    -Diyl -            Triyl               -tetrayl
                      -Ylidene          -Ylidyne         -Ylylidyne etc.
                                          -Ylylidene         -Diylidene
                                                                 -Diylylidene  

Catalogs Discussion Forums -> Organic Chemistry -> challenging NOMENCLATURE -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

Monovalent Divalent Trivalent Tetravalent etc.
-yl -Diyl -Triyl -tetrayl
-Ylidene -Ylidyne -Ylylidyne etc.
-Ylylidene -Diylidene
-Diylylidene

This is directly from an IUPAC document.
Catalogs Discussion Forums -> Trignometry -> stuck at dis question -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Thogh I could not find the answer by trigo----
But on simplification I got --
= 2
---------------------------
cos45 + sin 25
since for small angle(rad) sin x =x
Thus sin 25 =25xpi/180 = 0.436
Thus =2/(0.707+0.436)
=1.75
=(nearly) (3)^1/2 Ans
We can use this in case if we need this simplification in physics etc but not in Maths
Still trying to solve it.
 
 
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