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Community shelf Community shelf -> DEPRESSED?????JUST READ IT........ -> Go to message
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Good article- inspiring. Must read for all
Catalogs Discussion Forums -> Organic Chemistry -> Why is 2 degree carbocation more stable than 1 degree ? -> Go to message
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Due to +I effect and hyperconjugation of the CH3 grps.
General  Order is:
30>20=allylic=benzylic>10>CH3

Catalogs Discussion Forums -> Non IIT Institutes -> How was AIEEE 2009! Student Opinion Poll! -> Go to message
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Physics was avg, chem was easy, maths was toughgetting 330 what rank can i expect?
Catalogs Discussion Forums -> Organic Chemistry -> how can we differentiate between e1 and e2 reactions when a particular reaction is given to us? -> Go to message
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Interesting   ques.

Well, e1 proceeds via carbocation. So, any reaction which favours formation  of  carbocation will favour e1

e.g: Resonance stabilised cations(benzylic, allylic, or  even  cyclopropyl ring  stabilised)

        polar protic solvent

        high temp.

 

Now, e2  proceeds via transition  state.  So, factors  whiich stabilise the TS help e2

So, less substituted 1 degree carbon will  give e2. But here, substitution may get preferred in gas phase or non polar/ polar aprotic solvent

 In your ques, 2 degree alkyl bromide is  given. So, we will expect e1 with rearrangement

Catalogs Discussion Forums -> Organic Chemistry -> what is the increasing order of acidic character in different cases of CH3 group attached to phenol -> Go to message
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The alkyl grps hav a +I effect & also a hyperconjugative effectSo, the acidity is meta(only +I effect)>para(only hyperconj.)>ortho(=I as well as hyperconj.)
Catalogs Discussion Forums -> Physical Chemistry -> Ionisation Energy -> Go to message
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IE of any metal is directly proportional to the work function.
Catalogs Discussion Forums -> Integral Calculus -> question on integration -> Go to message
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[ ][ ]dx/{x(xn+1)}=?

(a) 1/2 log(1+x2)+C   (b) log(xn)+C   (c) log(1+xn)+C   (d)none of the above
 
 
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