Well, I think there will not be any particular (i.e. standard) direction of that car.
Let i and j be the unit vectors along E-N direction.
Say, vel of A = ai + bj ;
vel of B = mi + nj ;
vel of car = xi + yj
Now, A and B are moving in same direction and vel of B is twice that of A .....
i.e. m = 2a and n = 2b ..... as the direction remains same
Now vcar/man = vcar/ground - vman/ground
Thus for A: ( )i + 0j = (x-a)i + (y-b)j ..... i.e. y = b
Thus for B: 0i + ( )j = (x-m)i + (y-n)j ..... i.e. x = m
I've left the spaces blank .... as we know only the directions of relative motion ....
Thus, vel of car = mi + bj = 2ai + bj
And dir is tan-1(b/2a) .....
Let me know if I'm wrong ....