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Catalogs Discussion Forums -> Mechanics -> Projection from Parabolic surface -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
1 replies   
If it returns back to the same position after striking then it must have striked the parabola normally at (-1,1). Hence it must have been projected normally from (1,1).

slope of normal at (1,1) = -1/(dy/dx) = -1/2x (at x=1) = -1/2

Hence the angle of projection with horizontal is tan -1(1/2).
Catalogs Discussion Forums -> Organic Chemistry -> free radicals stability -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
4 replies   
Radical alkyl intermediates are stabilized by similar criteria as carbocations, the more substituted the radical center is, the more stable it is. This will direct their reactions: formation of a tertiary radical (R3C·) is favored over secondary (R2HC·) or primary (RH2C·). However, radicals next to functional groups, such as carbonyl, nitrile, and ether are even more stable than tertiary alkyl radicals.
Radicals attack double bonds, but unlike similar ions, they are slightly less directed by electrostatic interactions. For example, the reactivity of nucleophilic ions with ?,?-unsaturated compounds (C=C-C=O) is directed by the electron-withdrawing effect of the oxygen, resulting in a partial positive charge on the carbonyl carbon. There are two reactions that are observed in the ionic case: the carbonyl is attacked in a direct addition to carbonyl, or the vinyl is attacked in conjugate addition, and in either case, the charge on the nucleophile is taken by the oxygen. Radicals add rapidly to the double bond, and the resulting ?-radical carbonyl is relatively stable.
Catalogs Discussion Forums -> Integral Calculus -> indefinite integration -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
1 replies   
I think the question is :

I = {1+x+ (x+x2)}/{(x+1) + x} dx

Now rationalize it :

[{1+x+ (x+x2)}/{(x+1) + x}].[{(x+1) - x}/{(x+1) - x}]

= (1+x)1/2 - x1/2 + x(1+x)1/2 - x3/2 + x1/2 + x3/2 - x(1+x)1/2

= (1+x)1/2

Hence I = (1+x)1/2 dx = (2/3)(1+x)3/2 + c
 
Catalogs Discussion Forums -> Organic Chemistry -> organic fast help please !~!!!!!! -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
4 replies   
With mild oxidizing agent it will form CH3CHO.

With strong oxidizing agent it will form CH3COOH.

The difference is when it oxidized by stronger agent first it oxidizes to aldehyde and it further oxidizes to acid while with mild agent further oxidation will not take place after formation of aldehyde.
Catalogs Discussion Forums -> Electricity -> potential due to thin uniformly charged spherical shell -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
4 replies   
Use a concentric Gaussian sphere of radius r outside the shell.

E.dA = Qin/0

E(4r2) = Q/0

E = (1/40)(Q/r2)

V = infinityr (-Edr) = infinityr (-1/40)(Q/r2).dr

V = (1/40)(Q/r)
Catalogs Discussion Forums -> Inorganic Chemistry -> chiral centre -> Go to message
This Post 10 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]
3 replies   
The term chiral is used to describe an object which is non-superimposable on its mirror image.

A molecule is chiral if it cannot be superimposed on its mirror image the two mirror images of such a molecule are referred to as enantiomers. A mixture of equal amounts of the two enantiomers is said to be a racemic mixture.

Human hands are perhaps the most universally recognized example of chirality.

The two enantiomers of bromochlorofluoromethane
The two enantiomers of bromochlorofluoromethane

Here carbon atom is the centre of chirality.
Catalogs Discussion Forums -> Mechanics -> last minute preparation -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
6 replies   
Nobody knows the exact weightage of the topics asked in JEE. Instead try to revise your strong topics and do your best in the exam.

Himanshu had given some links , refer them for shortcuts.
Catalogs Discussion Forums -> Analytical Geometry -> finding inradius of right angled triangle -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
11 replies   
r = (area)/(semi-perimeter)

area = (1/2)(3)(4) = 6

semi-perimeter = (3+4+5)/2 = 6

Hence r = 6/6 = 1
Catalogs Discussion Forums -> About IITs and JEE -> eligibility for iit 2008 as a repeater -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
1 replies   
I think the that the eligibility criteria will remain as it is in JEE 2007. But nobody knows what plans the have. Even if there is a change in plan you will be provided with one time exception as it was the case last year. If your percentage is above 60 and you are confident , i would suggest you to take a drop.
Catalogs Discussion Forums -> Physical Chemistry -> bong angle -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
6 replies   
The shape of a molecule is determined by the number of groups of electrons around the central atom. The 'groups' might be a non-bonding single electron, a non-bonding or bonding pair of electrons, a double pair of bonding electrons or triple pair of bonding electrons etc. The electron 'groupings' repel to minimise the potential energy of the system i.e. to make the A-B-C angle as wide as possible.

Any lone pairs of non-bonding electrons on the central atom X, are closer to X than bond pairs because there is no Q atom attracting/sharing the lone pair electron charge.This will increase the repulsion between a lone pair of electrons on X and any other bonding/non-bonding on X.

In terms of electron pair repulsion: lone pair - lone pair > lone pair  - bond pair > bond pair - bond pair.

As the lone pair - 'other pair' repulsion increases, the angle between these pairs increases, so the Q-X-Q angle will be slightly reduced compared to what might be expected from the 'simple' geometry of the shape.
Catalogs Discussion Forums -> Integral Calculus -> please help!!!!!!!!!!!!!!!!!!!!!!!!i need to know this!!!!!!!!!! -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
2 replies   
In calculus, an antiderivative, primitive or indefinite integral of a function f is a function F whose derivative is equal to f, i.e., F ? = f. The process of solving for antiderivatives is antidifferentiation (or indefinite integration).

Antiderivatives are related to definite integrals through the fundamental theorem of calculus, and provide a convenient means for calculating the definite integrals of many functions.

They can be used to compute definite integrals, using the fundamental theorem of calculus: if F is an antiderivative of the integrable function f, then:

\int_a^b f(x)\,dx = F(b) - F(a).
Catalogs Discussion Forums -> Algebra -> time- work -> Go to message
This Post 2 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]
2 replies   
1 man in 1 day can perform 1/(24x16) work.
1 woman in 1 day can perform 1/(32x24) work.

Hence in 12 days 16 men and 16 women perform 12{16/(24x16) + 16/(32x24)} = 3/4 work

Let additional men required be x.
In remaining 2 days 1/4 amount of work is to be done.

Hence 2{(16+x)/(24x16) + 16/(32x24)} = 1/4

x = 24 additional men required.
Catalogs Discussion Forums -> Algebra -> least and greatest integral values -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
1 replies   
y = (x2+3x-40)/(x2+5x-14)

y = {(x-5)(x+8)}/{(x+7)(x-2)}

y < 0    when x
(-8,-7) (2,5)

Hence the least integral value of x for which y < 0 is 3.
Hence the greatest integral value of x for which y < 0 is 4.
Catalogs Discussion Forums -> Mechanics -> spring constant -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
2 replies   
Time period is given by T = 2(m/k)

Let mass of chair be M.
1 = 2(M/600)
M = 600/42

When a man of mass m sits on chair :
2.5 = 2(M+m/k)
M+m = 600(2.52/42)

Hence m = 600(2.52/42) - 600/42

Approx. m = 78.75 kg
Weight = 787.5 N
Catalogs Discussion Forums -> Mechanics -> ans given is cos(inverse)1/4 -> Go to message
This Post 7 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]
2 replies   
KE when it is striked = (1/2)m(52)

Suppose its velocity is u when it makes and angle with vertical.

Gain in KE = Loss in PE
(1/2)mu2 - (1/2)m(52) = mglcos
u2 = 25 + 40 cos

Force equation at maximum tension :

Tmax - mgcos = mu2/l

2mg - mgcos = mu2/l    (since Tmax = 2mg)

2mg - mgcos = m(25+40cos)/2

4 - 2cos = 2.5 + 4cos

6cos = 1.5

cos = 1.5/6 = 1/4

Hence = cos-1(1/4)

 
 
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