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There are five d-orbitals. Their shapes are - In an octahedral complex the ligands are arranged around a central metal ion along the x, y and z axes as shown below - As can be seen the dx2-y2 and dz2 orbitals overlap with the positions of the six ligands. This raises their energy relative to the other three d-orbitals The amount of splitting (DE) produced in a transition metal ions d-orbitals is affected by the ligand used in the complex. e.g. As can be seen from the equation above substitution of four water molecules by ammonia molecules in the complex causes the wavelengths of light absorbed to change, therefore changing the colour.
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thanx a lot ........Vinod
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HERE IS A GOOD FROMULA WHICH TAKES CARE OF OUR PROGRESS. Write the English alphabet from A to Z assigning them 1 to 26 numbers. | A | B | C | D | E | F | G | H | I | J | K | L | M | | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | | 14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | 22 | 23 | 24 | 25 | 26 | Now take a word and put the corresponding numbers for the letters. LUCK=47 the sum total of numerical luck is 47. That means it is not possible to achieve complete victory by luck alone. POWER=77 Power is also useless. It has its own pitfalls. MONEY=72 Money is also useless. Money can get U all luxuries but not prudence and wisdom. | K | N | O | W | L | E | D | G | E | | 11 | 14 | 15 | 23 | 12 | 5 | 4 | 7 | 5 | KNOWLEDGE=96 U may have knowledge, but u do not score cent per cent marks. U require something else 2 make a mark | H | A | R | D | W | O | R | D | | 8 | 1 | 18 | 4 | 23 | 15 | 18 | 11 | HARDWORK=98 Even hard work does not give u complete victory. Singly it is useless NOW, OBSERVE THE SECRETS OF COMPLETE VICTORY | A | T | T | I | T | U | D | E | | 1 | 20 | 20 | 9 | 20 | 21 | 4 | 5 | ATTITUDE=100 | D | I | S | C | I | P | L | I | N | E | | 4 | 9 | 19 | 3 | 9 | 16 | 12 | 9 | 14 | 5 | DISCIPLINE=100 Attitude and discipline are the paths that lead us to complete victory. 4 complete victories, the bases are knowledge and ha rd work, and when u suitably amend Ur attitude and go forward with discipline, victory is yours
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Rolling friction is caused primarily by the interference of small indentations formed as one surface rolls over another. This is the idea behind the frictional forces involved with wheels, cylinders, and spheres. In the ideal case of the wheel, we must first look at the forces acting on the wheel. In pure rolling motion friction is required to start, stop, change the motion of a wheel. Below we can see the frictional force necessary to begin motion, and get the wheel moving at a velocity v. In pure rolling motion, friction causes the wheel to catch and stops the sliding and slipping motion; for example when a car spins its tires, slipping is taking place, thus the frictional force works to stop the spinning out and causes the tires to catch and begin pure rolling motion.  The frictional force, f, the force required to slow the wheel produces a torque which tends to decrease the angular velocity, w. (The normal and gravitational forces produce no effect because their line of action is through the center of rotation.) However, the surface could not possibly have such an effect on the wheel once the wheel has achieved pure rolling motion and constant angular and linear velocity. Zero friction occurs only for horizontal motion at constant velocity, but it is non-zero for any case in which acceleration is occurring parallel to the direction of motion of the center of mass, as when the object is rolling-without-slipping up or down a sloped surface. If we consider the rotation as being about the center of mass of the object, then the frictional force must be in a direction to provide the torque necessary to decrease or increase the angular velocity, depending on whether the object is accelerating or decelerating, respectively. Note that the friction can be in the direction of motion (rolling downhill) or opposite to it (rolling uphill). In pure rolling motion there is no sliding or slipping, thus the contact points have no relative motion (no relative velocity). This results in a frictional force of zero. Therefore, the wheel will roll forward with constant velocity, v = Rw, where R is the radius of the wheel.  In the actual case of the rolling wheel, the free-body diagram is much different. Both the wheel and the surface will undergo deformations due to their particular elastic characteristics. At the contact points, the wheel flattens out while a small trench is formed in the surface. The normal force is now distributed over the actual contact area rather than the point just below the center of the wheel.  Furthermore, the wheel takes on a sort of plowing motion resulting in increased deformation at the front of the wheel, while the rear of the wheel undergoes little deformation which results in the majority of the normal force being located at the front. When the wheel and the surface deform there is a minute amount of slipping, but the majority of the force is due to static friction. The overall rolling friction results in a force at the center of the wheel and is parallel to the surface of contact, and is represented by the equation:  This resultant frictional force is still rearward acting (tending to contribute to the angular velocity), but the new distribution of the normal forces creates a net torque negating the rotational contribution of the friction and causing an overall deceleration of the wheel?s forward velocity. Also, the major source of energy losses during rolling motion is primarily due to the deformation that occurs when the two surfaces are compressed and relaxed. This continual process generates heat in both the wheel and the surface.
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i already hav these books with me.is this enough for my 12th studies.... or any other books???plz help me i hav only a year left for me . im not having any coaching classes. plz help me to study effectively... Mathematics Pradeep?s new course mathematics (Romesh Kumar) Text book of mathematics (s.sarna, G. Gupta, K. Garg) Krishna?s obj Question bank (R.K Gupta, J.P.Arya) and i hav some more books with previous q papers, mcq etc Physics PV?S Fundamental physics (K.S Pathania) Basic principles of physics (K.K Mohindroo) Pradeep?s fundamental phy (K.L Gomber, K.LGogia) Together with physics (S.Duggal, anilkumar) Chemistry Pradeep?s new course chem. Modern approach to chem. Calculations (Ramendra C.Mukerjee) Chem. MCQ (V Ahluwalia, A.K Ghosh) Krishna?s obj engineering chem. (B.K.Sharma) Chem. Text book (R.R Misra, Neeti Misra) Obj chem. (Arun Syamal)
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i already hav these books with me.is this enough for my 12th studies.... or any other books???plz help me i hav only a year left for me . im not having any coaching classes. plz help me to study effectively... Mathematics Pradeep?s new course mathematics (Romesh Kumar) Text book of mathematics (s.sarna, G. Gupta, K. Garg) Krishna?s obj Question bank (R.K Gupta, J.P.Arya) and i hav some more books with previous q papers, mcq etc Physics PV?S Fundamental physics (K.S Pathania) Basic principles of physics (K.K Mohindroo) Pradeep?s fundamental phy (K.L Gomber, K.LGogia) Together with physics (S.Duggal, anilkumar) Chemistry Pradeep?s new course chem. Modern approach to chem. Calculations (Ramendra C.Mukerjee) Chem. MCQ (V Ahluwalia, A.K Ghosh) Krishna?s obj engineering chem. (B.K.Sharma) Chem. Text book (R.R Misra, Neeti Misra) Obj chem. (Arun Syamal)
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Vijay........ ur ans is not correct
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The first tie in cricket history was b/w? a) Eng - Aus b) Aus-WI c)India - Aus d)Eng-pakistan
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no im from 'God's Own Country'
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hey Vijay !!!!!!! can i freeze iiittttttt?????/ |
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hi Karthiiiii good !!!!!! im giving one more chance wanna lifeline!!!!!!!!! computer plz ....... ooooh its not varanasi aaannnnnnnnddddddd not kolkata now can i freeze ur ans????????  |
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Topic: Games & Sports 1)Which country had won first world cricket cup? a) England b) West Indies c)Australia d) India 2)Shivaji hockey stadium is located in: a) Amritsar b) Varanasi c) Kolkata d) New Delhi 3) Who is known as "Tiger" in sports? a) Mohammad Ali b) Mansur Ali Pataudi c) Alexander Vormon answers....?????????? Continue.............
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WELL DONE......... SHUBHU!!!!!! SALUTE!!!!!!!
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Vriti Edustore
