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Catalogs Discussion Forums -> Organic Chemistry -> Organic Doubt,based on SN2 reaction -> Go to message
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If a reaction is carried out in a protic solvent, whose molecules have a hydrogen bonded to an oxygen or to a nitrogen, the larger atom is a better nucleophile in an SN2 reaction. In other words, the weaker base is the better nucleophile in a protic solvent. For example, the iodide ion is better than a fluoride ion as a nucleophile. However, if the reaction is carried out in an aprotic solvent, whose molecules do not have hydrogen bonded to an oxygen or to a nitrogen, then the stronger base is the better nucleophile. In this case, the fluoride ion is better than the iodide ion as a nucleophile.


Can u please explain this statement and why this is true???

Catalogs Discussion Forums -> Thermal Physics -> thermal doubt -> Go to message
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Actually the statement means that the liquid in glass thermometer shall show different readings,with different liquids,due to differences in various properties like Viscosity and Coefficient of Thermal Expansion.


While on the other hand,in gas thermometers we try using the properties of expansion of gases,to find the temperature and which overall is same for all gases(assuming they are ideal).V is directly prop.to T and hence u can say that gases(ideal Gases) expand on increase of temperature.

Catalogs Discussion Forums -> Physical Chemistry -> A Question... -> Go to message
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The pressure exerted by 12g of an ideal gas at temperature t degrees C,in a vessel of volume V litre is 1 atm.when temperature is increased by 10 degrees at same volume,pressure increases by 10%.Calculate t and V(molecular wt. of gas=120).

Community shelf Community shelf -> some imp.sites -> Go to message
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gr8!!! itna time kahaan se mila yaar!!!!
Catalogs Discussion Forums -> Counselling Zone -> BHOPAL tragedy -> Go to message
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Hey dont try anything new before the exam.................
And dont take tension.................
Whatever uve studied is all right for AIEEE,rest depends on problem solving skills.............
Catalogs Discussion Forums -> Trignometry -> Trigonometry IIT-JEE question -> Go to message
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Use ur knowledge of functions.....i.e.
here now sinx & cos x have values wihin the range [-1,1]...........
Now if we look at it.....cos 0=1 so,cos x is actually a decreasing funcion in the domain [0,pi]
While sin x is an increasing function since its value starts from sin 0=0..........
So,it is clear that for as x tends to zero cos x tends to be greater than sin x........
clearly from x belonging to [0,1],cos x should have greater values than sin x
so,cos(sin x)>=sin(cos x)
Catalogs Discussion Forums -> Electricity -> akward question -> Go to message
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Actually we'll have to delve into a bit higher concept of Electric Field(or Electrostatic Force Lines) Lines.Here in the diagram's first two parts we see that the field lines in case of first diagram terminate and in second diagram they do not .Hence the repulsion is dependent on termination of field lines,as per the diagrams,and the concept of Electric Field.
Catalogs Discussion Forums -> Trignometry -> Trigonometry-please explain -> Go to message
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Catalogs Discussion Forums -> Mechanics -> Doubt in law of conservation of energy!!!! -> Go to message
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This must be due to friction at the hinge.........We dont know how much energy is dissipiated due to that...............
Also we see that the coefficient of restitution is lesser than 1..........
Catalogs Discussion Forums -> Algebra -> A question on combinatorics,involving a bit of chess..... -> Go to message
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Q:How many ways can we put a white and a black king on a chessboard so that they do no attack each other???
Catalogs Discussion Forums -> Lounge -> GAME:RATE THE PIC -> Go to message
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9/10...
Catalogs Discussion Forums -> Mechanics -> can neone explain me the conservation of momentum and when it is used?? -> Go to message
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Conservation of momentum states that the momentum of an isolated system is conserved.i.e.when on a system there is no external force applied the initial net momentum of the system is equal to the final net momentum of the system.
If for example during a collision between two objects when there is no external force applied on the system,then we can use this law......
it is used in practically all of the problems on collisions
 
 
Catalogs Discussion Forums -> Thermal Physics -> Try this!! Thermodynamics question -> Go to message
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Using Parallax Method get the Radius of the sun-earth orbit,(it is easily possible) provided you have trigonomtry tables.Then,assume that the sun radiates energy at 2 cal/cm2 around this whole sphere of the Earth's radial orbit with surface area of 4*pi*r*r where r is radius of sun-Earth orbit.Total Energy=2c cal/cm2*surface area and then use Stefan's law to find final answer
Catalogs Discussion Forums -> Thermal Physics -> Question based on Thermal properties of matter -> Go to message
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At great heights in the atmosphere,if we send people without space suits(i.e Like they are in Earth) they are said to be dying of freezing....Why???
 
 
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