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Catalogs Discussion Forums -> Organic Chemistry -> acid chloride not reduced by diborane? -> Go to message
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Dear sir


i have following doubts


1. why acid chlorides are not reduced by diborane while carboxylic acids can be reduced.


2. why alpha hydroxy ketones give tollen's test.


3. Nucleophilic substitution on ester are easy with respect to carboxylic acid while alkoxide ion is a poor leaving group than hydroxide ion.


Catalogs Discussion Forums -> Organic Chemistry -> migratory aptitude in beyer villeger and pinacol reaction -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
1 replies   

sir i have few doubts in organic chemistry


1. why aldehyde do no give pinacol type reduction with Mg / water?


2. Migratory aptitude of groups in Beyer villeger oxidation including hydride and phenyl  with t, s ,p alkyl groups.


3. why acid chlorides are not reduced by diborane while carboxylic acids can be reduced.


4. why alpha hydroxy ketones give tollen's test.


5. Nucleophilic substitution on ester are easy with respect to carboxylic acid while alkoxide ion is a poor leaving group than hydroxide ion.

 
 
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