SIR, IM RAGHUVAR V.S
IM BASICALLY A LITTLE WEAK AT PHYSICS. IVE COMPLETED MY INTER FIRST YEAR BY NOW.
PLZ AVICE ME INM WHICH TOPICS I SHOULD STRENGTHEN.
ILL BE THANKFUL TO U ALL.
IM LACKING THE ABILITY OF A PROPER APPROACH TOWARDS ANY PROBLEM. PLZ HELP ME. I WANT TO LEARN.
THANKING YOU.
http://www.learnerstv.com/lectures.php?course=ltv008&cat=Physics- FOR PHYSICS
http://www.learnerstv.com/lectures.php?course=ltv011&cat=Chemistry-FOR CHEMISTRY
TRY THIS SITE//
THANX
HAI
im off to discuss an important topic, ie the pressure that is being imposed on students by their parents(though for a good cause)
see, nowadays competition has increased a lot. and this made students more conscious and their parentsz, MORE ANXIOUS.
we cant blame parents for this. they want to see us shine. but the child has to be given options and time to relax. but parents want their children to be with books for all the 24 hours.[THIS CASE IS NOT FOR ALL THE READERS]
pressure is building on the students. if this is the case, then there wont come out a positive result.
ALL THE COMMUNITY MEMBERS ARE WELCOME TO SUGGEST THEIR TIPS TO ANDF AMONG US, TO OVERCOME STRESS & PRESSURE AND HOW TO STUDY BETTER IN A PLANNED MANNER.
PLEASE TAKE THIS TOPIC SERIOUSLY AND PROCEED. THESE TIPS OF URS WILL SURELY BE HELPFUL TO THE WHOLE STUDENT COMMUNITY.
THANK YOU ALL.
http://youtube.com/watch?v=xdZsiBwkmf0&feature=related
these set of videos are nice.!
hope they help the members of this community.
http://www.mhhe.com/physsci/chemistry/carey/student/olc/ch02summary.html
this site, hopefully, might be useful to learn CHEMISTRY, even organic cchemistry.
SyllabusforSecondaryandHigherSecondaryLevels C
Syllabus
for
Secondary
and
Higher
Levels
C
HECMHEMIISTSRYTRY(CLASSES XI–XII)RationaleHigher Secondary Stage is the most crucial stage of school education because at this stage specialiseddiscipline based, content oriented courses are introduced. Students reach this stage after 10 years ofgeneral education and opt for Chemistry with a purpose of mostly for pursuing their career in basicsciences or professional courses like medicines, engineering, technology and studying courses in appliedareas of science and technology at tertiary level. Therefore, at this stage, there is a need to providelearners with sufficient conceptual background of Chemistry, which will make them competent tomeet the challenges of academic and professional courses after the higher secondary stage.National Curriculum Framework for School Education – 2005 recommends a disciplinary approachwith appropriate rigour and depth with the care that syllabus is not heavy and at the same time it iscomparable to the international level. It emphasizes a coherent focus on important ideas within thediscipline that are properly sequenced to optimize learning. It recommends that theoretical componentof Higher Secondary Science should emphasize on problem solving methods and the awareness ofhistorical development of key concepts of science be judiciously integrated into content. The presentexercise of syllabus development in Chemistry at Higher Secondary Stage is based on this framework.Salient features of the present syllabus are thus:• Some background of Chemistry from secondary stage is assumed; however, no specificknowledge of topics in Chemistry is pre-supposed.• The course is self-contained and broadly covers fundamental concepts of Chemistry.• Attempt has been made to see discipline of Chemistry does not remain only the science offacts but becomes related to modern applications in the world around us.• The syllabus provides logical sequencing of the ‘Units’ of the subject matter with properplacement of concepts with their linkages for better understanding.• Emphasis has been on promoting process – skills, problem solving abilities and applicationsof concepts of Chemistry useful in real life situation for making learning of Chemistry morerelevant, meaningful and interesting.• An effort has been made on the basis of feedback, to remove repetition besides reducing thecontent by suitably integrating the different content areas.• Practical syllabus has two components. There are core experiments to be undertaken by thestudents in the classroom and will be part of examination while each student will carry out oneinvestigatory project and submit the report for the examination.With this background, the Chemistry curriculum at the higher secondary stage attempts to• promote understanding of basic principles in Chemistry while retaining the excitement in Chemistry;• develop an interest in students to study Chemistry as discipline;• strengthen the concepts developed at the secondary stage and to provide firm foundation forfurther learning of Chemistry at tertiary level more effectively;23SyllabusforSecondaryandHigherSecondaryLevelsXI• develop positive scientific attitude, and appreciate contribution of Chemistry towards theimprovement of quality of human life;• develop problem solving skills and nurture curiosity, aesthetic sense and creativity;• inculcate values of honesty, integrity, cooperation, concern for life and preservation of the environment;• make the learner realise the interface of Chemistry with other disciplines of science such asPhysics, Biology, Geology, etc;• equip students to face challenges related to health, nutrition, environment, population, whetherindustries and agriculture.CHEMISTRY CLASS XITheory Total Periods 180Unit I:Some Basic Concepts of Chemistry (Periods 14)General IntroductionHistorical approach to particulate nature of matter, laws of chemical combination,theoryAtomic and molecular masses. Mole concept and molar mass; percentage composition and empiricaland molecular formula; chemical reactions, stoichiometry and calculations based on stoichiometry.: Importance and scope of chemistry.Dalton’s atomic: concept of elements, atoms and molecules.Unit II:Structure of Atom (Periods 16)Discovery of electron, proton and neutron; atomic number, isotopes and isobars. Thompson’smodel and its limitations, Rutherford’s model and its limitations, Bohr’s model and its limitations,concept of shells and subshells, dual nature of matter and light, de Broglie’s relationship, Heisenberguncertainty principle, concept of orbitals, quantum numbers, shapes offor filling electrons in orbitals – Aufbau principle, Pauli exclusion principle and Hund’s rule,electronic configuration of atoms, stability of half filled and completely filled orbitals.s, p, and d orbitals, rulesUnit III:Classification of Elements and Periodicity in Properties (Periods 8)Significance of classification, brief history of the development of periodic table,modern periodic law and the present form of periodic table, periodictrends in properties of elements – atomic radii, ionic radii,inert gas radii, ionization enthalpy, electron gain enthalpy,electronegativity, valence.Unit IV:Chemical Bonding and Molecular Structure(Periods 16)Valence electrons, ionic bond, covalent bond, bond parameters,Lewis structure, polar character of covalent bond, covalent characterof ionic bond, valence bond theory, resonance, geometry ofcovalent molecules, VSEPR theory, concept of hybridizationinvolvings, p and d orbitals and shapes of some simple molecules,SyllabusforSecondaryandHigherSecondaryLevels24molecular orbital theory of homonuclear diatomic molecules (qualitative idea only),hydrogen bond.Unit V:States of Matter: Gases and Liquids (Periods 14)Three states of matter, intermolecular interactions, type of bonding, melting and boiling points,role of gas laws in elucidating the concept of the molecule, Boyle’s law, Charles’ law, Gay Lussac’slaw, Avogadro’s law, ideal behaviour, empirical derivation of gas equation, Avogadro’s number,ideal gas equation, deviation from ideal behaviour, liquefaction of gases, critical temperature.Liquid State – Vapour pressure, viscosity and surface tension (qualitative idea only, nomathematical derivations).Unit VI:Thermodynamics (Periods 16)Concepts of system, types of systems, surroundings, work, heat, energy, extensive and intensiveproperties, state functions.First law of thermodynamics – internal energy and enthalpy, heat capacity and specific heat,measurement ofcombustion, formation, atomization, sublimation, phase transition, ionization, and dilution.Introduction of entropy as a state function, free energy change for spontaneous and nonspontaneousprocess, equilibrium.ΔU and ΔH, Hess’s law of constant heat summation, enthalpy of: bond dissociation,Unit VII:Equilibrium (Periods 16)Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of massaction, equilibrium constant, factors affecting equilibrium – Le Chatelier’s principle; ionicequilibrium – ionization of acids and bases, strong and weak electrolytes, degree of ionization,concept of pH. Hydrolysis of salts (elementary idea), buffer solutions, solubility product, commonion effect (with illustrative examples).Unit VIII:Redox Reactions (Periods 6)Concept of oxidation and reduction, redox reactions,oxidation number, balancing redox reactions, applicationsof redox reactions.Unit IX:Hydrogen (Periods 8)Position of hydrogen in periodic table, occurrence, isotopes, preparation, properties and uses ofhydrogen; hydrides – ionic, covalent and interstitial; physical and chemical properties of water,heavy water; hydrogen peroxide – preparation, reactions and structure; hydrogen as a fuel.Unit X:s-Block Elements (Alkali and Alkaline Earth Metals) (Periods 14)Group 1 and Group 2 elements:General introduction, electronic configuration, occurrence, anomalous properties of the firstelement of each group, diagonal relationship, trends in the variation of properties (such as ionizationenthalpy, atomic and ionic radii), trends in chemical reactivity with oxygen, water, hydrogen andhalogens; uses.Preparation and properties of some important compounds:Sodium carbonate, sodium chloride, sodium hydroxide and sodium hydrogen carbonate, biologicalimportance of sodium and potassium.CaO, CaCO3, and industrial use of lime and limestone, biological importance of Mg and Ca.25SyllabusforSecondaryandHigherSecondaryLevelsUnit XI:Some p-Block Elements (Periods 16)General Introduction to p-Block ElementsGroup 13 elements:oxidation states, trends in chemical reactivity, anomalous properties of first element of the group;Boron – physical and chemical properties, some important compounds: borax, boric acids,boron hydrides. Aluminium: uses, reactions with acids and alkalies.General introduction, electronic configuration, occurrence, variation of properties,Group 14 elements:properties, oxidation states, trends in chemical reactivity, anomalous behaviour of first element.Carbon – catenation, allotropic forms, physical and chemical properties; uses of some importantcompounds: oxides.Important compounds of silicon and a few uses: silicon tetrachloride , silicones, silicates andzeolites.General introduction, electronic configuration, occurrence, variation ofUnit XII:Organic Chemistry – Some Basic Principles and Techniques (Periods 14)General introduction, methods of purification, qualitative and quantitative analysis, classificationand IUPAC nomenclature of organic compounds.Electronic displacements in a covalent bond: inductive effect, electromeric effect, resonanceand hyper conjugation.Homolytic and heterolytic fission of a covalent bond: free radicals, carbocations, carbanions;electrophiles and nucleophiles, types of organic reactionsUnit XIII:Hydrocarbons (Periods 16)Classification of hydrocarbonsAlkanesreactions including free radical mechanism of halogenation, combustion and pyrolysis.: Nomenclature, isomerism, conformations (ethane only), physical properties, chemicalAlkenesproperties, methods of preparation; chemical reactions: addition of hydrogen, halogen, water,hydrogen halides (Markovnikov’s addition and peroxide effect), ozonolysis, oxidation, mechanismof electrophilic addition.: Nomenclature, structure of double bond (ethene), geometrical isomerism, physicalAlkynespreparation, chemical reactions: acidic character of alkynes, addition reaction of – hydrogen,halogens, hydrogen halides and water.: Nomenclature, structure of triple bond (ethyne), physical properties, methods ofAromatic hydrocarbonschemical properties: mechanism of electrophilic substitution – nitration sulphonation, halogenation,Friedel Craft’s alkylation and acylation; directive influence of functional group in mono-substitutedbenzene; carcinogenicity and toxicity.: Introduction, IUPAC nomenclature; Benzene: resonance, aromaticity;Unit XIV:Environmental Chemistry (Periods 6)Environmental pollutionmajor atmospheric pollutants; acid rain, ozone and its reactions, effects of depletion of ozone: Air, water and soil pollution, chemical reactions in atmosphere, smogs,SyllabusforSecondaryandHigherSecondaryLevels26layer, greenhouse effect and global warming – pollution due to industrial wastes; green chemistryas an alternative tool for reducing pollution, strategy for control of environmental pollution.Practicals Total Periods 60Micro-chemical methods are available for several of the practical experiments. Wherever possiblesuch techniques should be used.A.Basic Laboratory Techniques (Periods 2)1. Cutting glass tube and glass rod2. Bending a glass tube3. Drawing out a glass jet4. Boring a corkB.Characterisation and Purification of Chemical Substance (Periods 6)1. Determination of melting point of organic compound.2. Determination of boiling point of organic compound.3. Crystallization involving impure sample of any one of the following: Alum, Coppersulphate, Benzoic acid.C.Experiments Related to pH Change (Periods 6)(a) Any one of the following experiments:• Determination of pH of some solutions obtained from fruit juices, solutions of knownand varied concentrations of acids, bases and salts using pH paper or universal indicator.• Comparing the pH of solutions of strong and weak acid of same concentration.• Study the pH change in the titration of a strong acid with a strong base using universalindicator.(b) Study of pH change by common-ion effect in case of weak acids and weak bases.D.Chemical Equilibrium (Periods 4)One of the following experiments:(a) Study the shift in equilibrium between ferric ions and thiocynate ions by increasing/decreasing the concentration of either ions.(b) Study the shift in equilibrium between [Co (Hconcentration of either of the ions.2O)6]2+ and chloride ions by changing theE.Quantitative Estimation (Periods 16)• Using a chemical balance.• Preparation of standard solution of oxalic acid.• Determination of strength of a given solution of sodium hydroxide by titrating it againststandard solution of oxalic acid.• Preparation of standard solution of sodium carbonate.27SyllabusforSecondaryandHigherSecondaryLevelsXII• Determination of strength of a given solution of hydrochloric acid by titrating it againststandard sodium carbonate solution.F.Qualitative Analysis (Periods 16)Determination of one anion and one cation in a given saltCations – PbMg42+, Cu2+, As3+, Al3+, Fe3+, Mn2+, Ni2+, Zn2+, Co2+, Ca2+, Sr2+, Ba2+,2+, NH+Anions – CO2– 3, S2–, SO2– 3, SO2– 4, NO– 2, NO– 3, Cl–, Br–, I–, PO3– 4, C2O2– 4 CH3COO–(Note : Insoluble salts excluded)Project(Periods 10)Scientific investigations involving laboratory testing and collecting information from other sources.A few suggested projects• Checking the bacterial contamination in drinking water by testing sulphide ions.• Study of the methods of purification of water.• Testing the hardness, presence of iron, fluoride, chloride etc. depending upon the regionalvariation in drinking water and the study of causes of presences of these ions abovepermissible limit (if any)• Investigation of the foaming capacity of different washing soaps and the effect of addition ofsodium carbonate on them.• Study of the acidity of different samples of the tea leaves.• Determination of the rate of evaporation of different liquids.• Study of the effect of acids and bases on the tensile strength of fibers.• Analysis of fruit and vegetable juices for their acidity.Note:with the approval of the teacher.Any other investigatory project, which involves about 10 periods of work, can be chosenCHEMISTRY CLASS XIITheory Total Periods 60Unit I:Solid State (Periods 12)Classification of solids based on different binding forces: molecular, ionic, covalent and metallicsolids, amorphous and crystalline solids (elementary idea), unit cell in two dimensional and threedimensional lattices, calculation of density of unit cell, packing in solids, voids, number of atomsper unit cell in a cubic unit cell, point defects, electrical and magnetic properties.SyllabusforSecondaryandHigherSecondaryLevels28Unit II:Solutions (Periods 12)Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gasesin liquids, solid solutions, colligative properties – relative lowering of vapour pressure, elevation ofB.P., depression of freezing point, osmotic pressure, determination of molecular masses usingcolligative properties, abnormal molecular mass.Unit III:Electrochemistry (Periods 14)Redox reactions; conductance in electrolytic solutions, specific and molar conductivity variationsof conductivity with concentration, Kohlrausch’s Law, electrolysis and laws of electrolysis(elementary idea), dry cell – electrolytic cells and Galvanic cells; lead accumulator, EMF of acell, standard electrode potential, Nernst equation and its application to chemical cells, fuelcells; corrosion.Unit IV:Chemical Kinetics (Periods 12)Rate of a reaction (average and instantaneous), factors affecting rates of reaction: concentration,temperature, catalyst; order and molecularity of a reaction; rate law and specific rate constant,integrated rate equations and half life (only for zero and first order reactions); concept of collisiontheory (elementary idea, no mathematical treatment).Unit V:Surface Chemistry (Periods 8)Adsorptioncatalysis: homogenous and heterogeneous, activity and selectivity: enzyme catalysis; colloidal state:distinction between true solutions, colloids and suspensions; lyophillic, lyophobic multimolecularand macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement,electrophoresis, coagulation; emulsions – types of emulsions.: Physisorption and chemisorption; factors affecting adsorption of gases on solids;Unit VI:General Principles and Processes of Isolation of Elements (Periods 8)Principles and methods of extractionrefining; occurrence and principles of extraction of aluminium, copper, zinc and iron.: concentration, oxidation, reduction electrolytic method andUnit VII:p-Block Elements (Periods 14)Group 15 elementstrends in physical and chemical properties; nitrogen – preparation, properties and uses; compoundsof nitrogen: preparation and properties of ammonia and nitric acid, oxides of nitrogen (structureonly); Phosphorous – allotropic forms; compounds of phosphorous: preparation and propertiesof phosphine, halides (PCl: General introduction, electronic configuration, occurrence, oxidation states,3, PCl5) and oxoacids (elementary idea only).Group 16 elementstrends in physical and chemical properties; dioxygen: preparation, properties and uses; simpleoxides; ozone. Sulphur – allotropic forms; compounds of sulphur: preparation, properties anduses of sulphur dioxide; sulphuric acid: industrial process of manufacture, properties and uses,oxoacids of sulphur (structures only).: General introduction, electronic configuration, oxidation states, occurrence,29SyllabusforSecondaryandHigherSecondaryLevelsGroup 17 elementstrends in physical and chemical properties; compounds of halogens: preparation, propertiesand uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens(structures only).: General introduction, electronic configuration, oxidation states, occurrence,Group 18 elementsand chemical properties, uses.: General introduction, electronic configuration, occurrence, trends in physicalUnit VIII:d and f Block Elements (Period 14)General introduction, electronic configuration, occurrence and characteristics of transition metals,general trends in properties of the first row transition metals – metallic character, ionizationenthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitialcompounds, alloy formation. Preparation and properties of K2Cr2O7 and KMnO4.Lanthanoidscontraction.: electronic configuration, oxidation states, chemical reactivity and lanthanoidActinoids: Electronic configuration, oxidation states.Unit IX:Coordination Compounds (Period 12)Coordination compoundsand shapes, IUPAC nomenclature of mononuclear coordination compounds, bonding;isomerism, importance of coordination compounds (in qualitative analysis, extraction ofmetals and biological systems).: Introduction, ligands, coordination number, colour, magnetic propertiesUnit X:Haloalkanes and Haloarenes (Periods 12)Haloalkanesof substitution reactions.: Nomenclature, nature of C-X bond, physical and chemical properties, mechanismHaloarenesmonosubstituted compounds only).Uses and environmental effects of – dichloromethane, trichloromethane, tetrochloromethane,iodoform, freons, DDT.: Nature of C-X bond, substitution reactions (directive influence of halogen forUnit XI:Alcohols, Phenols and Ethers (Periods 12)Alcoholsalcohols only); identification of primary, secondary and tertiary alcohols;mechanism of dehydration, uses, some important compounds –methanol and ethanol.: Nomenclature, methods of preparation, physical and chemical properties (of primaryPhenolschemical properties, acidic nature of phenol, electrophillicsubstitution reactions, uses of phenols.: Nomenclature, methods of preparation, physical andEthersand chemical properties, uses.: Nomenclature, methods of preparation, physicalSyllabusforSecondaryandHigherSecondaryLevels30Unit XII:and Carboxylic AcidsAldehydes, Ketones(Periods 12)Aldehydes and Ketonesnature of carbonyl group, methodsof preparation, physical and chemical properties,and mechanism of nucleophilic addition,reactivity of alpha hydrogen in aldehydes; uses.: Nomenclature,Carboxylic Acidsphysical and chemical properties; uses.: Nomenclature, acidic nature, methods of preparation,Unit XIII:Organic Compounds Containing Nitrogen (Periods 10)Aminesproperties, uses, identification of primary secondary and tertiary amines.: Nomenclature, classification, structure, methods of preparation, physical and chemicalCyanides and Isocyanideswill be mentioned at relevant places in context.Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.Unit XIV:Biomolecules (Periods 12)Carbohydratesoligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen);importance.: Classification (aldoses and ketoses), monosaccharides (glucose and fructose),Proteinsstructure, secondary structure, tertiary structure and quaternary structure (qualitative idea only),denaturation of proteins; enzymes.: Elementary idea of α - amino acids, peptide bond, polypeptides, proteins, primaryVitamins: Classification and functions.Nucleic Acids: DNA and RNA .Unit XV:Polymers (Periods 8)Classificationcopolymerization. Some important polymers: natural and synthetic like polythene, nylon, polyesters,bakelite, rubber.: Natural and synthetic, methods of polymerization (addition and condensation),Unit XVI:Chemistry in Everyday Life (Periods 8)1. Chemicals in medicines – analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials,antifertility drugs, antibiotics, antacids, antihistamines.2. Chemicals in food – preservatives, artificial sweetening agents.3. Cleansing agents – soaps and detergents, cleansing action.Practicals Total Periods 60Microchemical methods are available for several of the practical experiments. Wherever possiblesuch techniques should be used.31SyllabusforSecondaryandHigherSecondaryLevelsA.Surface Chemistry (Periods 5)(a) Preparation of one lyophilic and one lyophobic sol.Lyophilic sol: starch, egg albumin and gum.Lyophobic sol(b) Dialysis of sol prepared in (a) above.(c) Study of the role of emulsifying agent in stabilizing the emulsions of different oils.: aluminium hydroxide, ferric hydroxide, arsenious sulphide.B.Chemical Kinetics (Periods 4)(a) Effect of concentration and temperature on the rate of reaction between sodiumthiosulphate and hydrochloric acid.(b) Study of reaction rates of any one of the following:(i) Reaction of iodide ion with hydrogen peroxide at room temperature using differentconcentration of iodide ions.(ii) Reaction between potassium iodate (KIOstarch solution as indicator (clock reaction).3) and sodium sulphite (Na2SO3) usingC.Thermochemistry (Periods 4)Any one of the following experiments:(a) Enthalpy of dissolution of copper sulphate or potassium nitrate.(b) Enthalpy of neutralization of strong acid (HCl) and strong base (NaOH).(c) Determination of enthalpy change during interaction (Hydrogen bond formation) betweenacetone and chloroform.D.Electrochemistry (Periods 2)Variation of cell potential in Zn/Zn(CuSO2+//Cu2+/Cu with change in concentration of electrolytes4 or ZnSO4) at room temperature.E.Chromatography (Periods 2)(a) Separation of pigments from extracts of leaves and flowers by paper chromatographyand determination of R(b) Separation of constituents present in an inorganic mixture containing two cations only(constituents having wide difference in Rf values.f values to be provided).F.Preparation of Inorganic Compounds (Periods 4)(a) Preparation of double salt of ferrous ammonium sulphate or potash alum.(b) Preparation of potassium ferric oxalate.G.Preparation of Organic Compounds (Periods 2)Preparation of any one of the following compounds:(a) Acetanilide(b) Di-benzal acetoneSyllabusforSecondaryandHigherSecondaryLevels32(c)(d) Aniline yellow or 2-Napththol aniline dye.p-Nitroacetanilide.H.Test for the Functional Groups Present in Organic Compounds (Periods 5)Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (primary) groups.I.Presence in given Food StuffsStudy of Carbohydrates, Fats and Proteins in Pure Form and Detection of their(Periods 4)J.against a Standard Solution ofDetermination of Concentration/Molarity of KMnO4 Solution by Titrating it(Periods 8)(a) Oxalic acid(b) Ferrous ammonium sulphate(Students will be required to prepare standard solutions by weighing themselves).K.Qualitative Analysis (Periods 10)Determination of one anion and one cation in a given salt.Cations – PbMg42+, Cu2+, As3+, Al3+, Fe3+, Mn2+, Ni2+, Zn2+, Co2+, Ca2+, Sr2+, Ba2+,2+, NH+Anions – CO2– 3, S2–, SO2– 3, SO2– 4, NO– 2, NO– 3, Cl–, Br–, I–, PO3– 4, C2 O2– 4 CH3COO–(Note : Insoluble salts excluded)Project (Periods 10)Scientific investigations involving laboratory testing and collecting information from other sources.A few suggested projects• Study of presence of oxalate ions in guava fruit at different stages of ripening.• Study of quantity of casein present in different samples of milk.• Preparation of soybean milk and its comparison with the natural milk with respect to curdformation, effect of temperature, etc.• Study of the effect of potassium bisulphate as food preservative under various conditions(temperature, concentration, time etc.)• Study of digestion of starch by salivary amylase and effect of pH and temperature on it.• Comparative study of the rate of fermentation of following materials: wheat flour, gramflour, potato juice, carrot juice etc.• Extraction of essential oils present in• Study of common food adulterants in fat, oil, butter, sugar, turmeric powder, chilli powderand pepper.Saunf (aniseed), Ajwain (carum), Illaichi (cardamom).Notewith the approval of the teacher.: Any other investigatory project, which involves about 10 periods of work, can be chosen
(CLASSES XI–XII)
Rationale
Higher Secondary Stage is the most crucial stage of school education because at this stage specialised
discipline based, content oriented courses are introduced. Students reach this stage after 10 years of
general education and opt for Chemistry with a purpose of mostly for pursuing their career in basic
sciences or professional courses like medicines, engineering, technology and studying courses in applied
areas of science and technology at tertiary level. Therefore, at this stage, there is a need to provide
learners with sufficient conceptual background of Chemistry, which will make them competent to
meet the challenges of academic and professional courses after the higher secondary stage.
National Curriculum Framework for School Education – 2005 recommends a disciplinary approach
with appropriate rigour and depth with the care that syllabus is not heavy and at the same time it is
comparable to the international level. It emphasizes a coherent focus on important ideas within the
discipline that are properly sequenced to optimize learning. It recommends that theoretical component
of Higher Secondary Science should emphasize on problem solving methods and the awareness of
historical development of key concepts of science be judiciously integrated into content. The present
exercise of syllabus development in Chemistry at Higher Secondary Stage is based on this framework.
Salient features of the present syllabus are thus:
• Some background of Chemistry from secondary stage is assumed; however, no specific
knowledge of topics in Chemistry is pre-supposed.
• The course is self-contained and broadly covers fundamental concepts of Chemistry.
• Attempt has been made to see discipline of Chemistry does not remain only the science of
facts but becomes related to modern applications in the world around us.
• The syllabus provides logical sequencing of the ‘Units’ of the subject matter with proper
placement of concepts with their linkages for better understanding.
• Emphasis has been on promoting process – skills, problem solving abilities and applications
of concepts of Chemistry useful in real life situation for making learning of Chemistry more
relevant, meaningful and interesting.
• An effort has been made on the basis of feedback, to remove repetition besides reducing the
content by suitably integrating the different content areas.
• Practical syllabus has two components. There are core experiments to be undertaken by the
students in the classroom and will be part of examination while each student will carry out one
investigatory project and submit the report for the examination.
With this background, the Chemistry curriculum at the higher secondary stage attempts to
• promote understanding of basic principles in Chemistry while retaining the excitement in Chemistry;
• develop an interest in students to study Chemistry as discipline;
• strengthen the concepts developed at the secondary stage and to provide firm foundation for
further learning of Chemistry at tertiary level more effectively;
23
XI
• develop positive scientific attitude, and appreciate contribution of Chemistry towards the
improvement of quality of human life;
• develop problem solving skills and nurture curiosity, aesthetic sense and creativity;
• inculcate values of honesty, integrity, cooperation, concern for life and preservation of the environment;
• make the learner realise the interface of Chemistry with other disciplines of science such as
Physics, Biology, Geology, etc;
• equip students to face challenges related to health, nutrition, environment, population, whether
industries and agriculture.
Theory Total Periods 180
Unit I:
General Introduction
Historical approach to particulate nature of matter, laws of chemical combination,
theory
Atomic and molecular masses. Mole concept and molar mass; percentage composition and empirical
and molecular formula; chemical reactions, stoichiometry and calculations based on stoichiometry.
Unit II:
Discovery of electron, proton and neutron; atomic number, isotopes and isobars. Thompson’s
model and its limitations, Rutherford’s model and its limitations, Bohr’s model and its limitations,
concept of shells and subshells, dual nature of matter and light, de Broglie’s relationship, Heisenberg
uncertainty principle, concept of orbitals, quantum numbers, shapes of
for filling electrons in orbitals – Aufbau principle, Pauli exclusion principle and Hund’s rule,
electronic configuration of atoms, stability of half filled and completely filled orbitals.
Unit III:
Significance of classification, brief history of the development of periodic table,
modern periodic law and the present form of periodic table, periodic
trends in properties of elements – atomic radii, ionic radii,
inert gas radii, ionization enthalpy, electron gain enthalpy,
electronegativity, valence.
Unit IV:
(Periods 16)
Valence electrons, ionic bond, covalent bond, bond parameters,
Lewis structure, polar character of covalent bond, covalent character
of ionic bond, valence bond theory, resonance, geometry of
covalent molecules, VSEPR theory, concept of hybridization
involving
24
molecular orbital theory of homonuclear diatomic molecules (qualitative idea only),
hydrogen bond.
Unit V:
Three states of matter, intermolecular interactions, type of bonding, melting and boiling points,
role of gas laws in elucidating the concept of the molecule, Boyle’s law, Charles’ law, Gay Lussac’s
law, Avogadro’s law, ideal behaviour, empirical derivation of gas equation, Avogadro’s number,
ideal gas equation, deviation from ideal behaviour, liquefaction of gases, critical temperature.
Liquid State – Vapour pressure, viscosity and surface tension (qualitative idea only, no
mathematical derivations).
Unit VI:
Concepts of system, types of systems, surroundings, work, heat, energy, extensive and intensive
properties, state functions.
First law of thermodynamics – internal energy and enthalpy, heat capacity and specific heat,
measurement of
combustion, formation, atomization, sublimation, phase transition, ionization, and dilution.
Introduction of entropy as a state function, free energy change for spontaneous and nonspontaneous
process, equilibrium.
Unit VII:
Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of mass
action, equilibrium constant, factors affecting equilibrium – Le Chatelier’s principle; ionic
equilibrium – ionization of acids and bases, strong and weak electrolytes, degree of ionization,
concept of pH. Hydrolysis of salts (elementary idea), buffer solutions, solubility product, common
ion effect (with illustrative examples).
Unit VIII:
Concept of oxidation and reduction, redox reactions,
oxidation number, balancing redox reactions, applications
of redox reactions.
Unit IX:
Position of hydrogen in periodic table, occurrence, isotopes, preparation, properties and uses of
hydrogen; hydrides – ionic, covalent and interstitial; physical and chemical properties of water,
heavy water; hydrogen peroxide – preparation, reactions and structure; hydrogen as a fuel.
Unit X:
Group 1 and Group 2 elements:
General introduction, electronic configuration, occurrence, anomalous properties of the first
element of each group, diagonal relationship, trends in the variation of properties (such as ionization
enthalpy, atomic and ionic radii), trends in chemical reactivity with oxygen, water, hydrogen and
halogens; uses.
Preparation and properties of some important compounds:
Sodium carbonate, sodium chloride, sodium hydroxide and sodium hydrogen carbonate, biological
importance of sodium and potassium.
CaO, CaCO
25
Unit XI:
General Introduction to p-Block Elements
Group 13 elements:
oxidation states, trends in chemical reactivity, anomalous properties of first element of the group;
Boron – physical and chemical properties, some important compounds: borax, boric acids,
boron hydrides. Aluminium: uses, reactions with acids and alkalies.
Group 14 elements:
properties, oxidation states, trends in chemical reactivity, anomalous behaviour of first element.
Carbon – catenation, allotropic forms, physical and chemical properties; uses of some important
compounds: oxides.
Important compounds of silicon and a few uses: silicon tetrachloride , silicones, silicates and
zeolites.
Unit XII:
General introduction, methods of purification, qualitative and quantitative analysis, classification
and IUPAC nomenclature of organic compounds.
Electronic displacements in a covalent bond: inductive effect, electromeric effect, resonance
and hyper conjugation.
Homolytic and heterolytic fission of a covalent bond: free radicals, carbocations, carbanions;
electrophiles and nucleophiles, types of organic reactions
Unit XIII:
Classification of hydrocarbons
Alkanes
reactions including free radical mechanism of halogenation, combustion and pyrolysis.
Alkenes
properties, methods of preparation; chemical reactions: addition of hydrogen, halogen, water,
hydrogen halides (Markovnikov’s addition and peroxide effect), ozonolysis, oxidation, mechanism
of electrophilic addition.
Alkynes
preparation, chemical reactions: acidic character of alkynes, addition reaction of – hydrogen,
halogens, hydrogen halides and water.
Aromatic hydrocarbons
chemical properties: mechanism of electrophilic substitution – nitration sulphonation, halogenation,
Friedel Craft’s alkylation and acylation; directive influence of functional group in mono-substituted
benzene; carcinogenicity and toxicity.
Unit XIV:
Environmental pollution
major atmospheric pollutants; acid rain, ozone and its reactions, effects of depletion of ozone
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layer, greenhouse effect and global warming – pollution due to industrial wastes; green chemistry
as an alternative tool for reducing pollution, strategy for control of environmental pollution.
Practicals Total Periods 60
Micro-chemical methods are available for several of the practical experiments. Wherever possible
such techniques should be used.
A.
1. Cutting glass tube and glass rod
2. Bending a glass tube
3. Drawing out a glass jet
4. Boring a cork
B.
1. Determination of melting point of organic compound.
2. Determination of boiling point of organic compound.
3. Crystallization involving impure sample of any one of the following: Alum, Copper
sulphate, Benzoic acid.
C.
(a) Any one of the following experiments:
• Determination of pH of some solutions obtained from fruit juices, solutions of known
and varied concentrations of acids, bases and salts using pH paper or universal indicator.
• Comparing the pH of solutions of strong and weak acid of same concentration.
• Study the pH change in the titration of a strong acid with a strong base using universal
indicator.
(b) Study of pH change by common-ion effect in case of weak acids and weak bases.
D.
One of the following experiments:
(a) Study the shift in equilibrium between ferric ions and thiocynate ions by increasing/
decreasing the concentration of either ions.
(b) Study the shift in equilibrium between [Co (H
concentration of either of the ions.
E.
• Using a chemical balance.
• Preparation of standard solution of oxalic acid.
• Determination of strength of a given solution of sodium hydroxide by titrating it against
standard solution of oxalic acid.
• Preparation of standard solution of sodium carbonate.
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XII
• Determination of strength of a given solution of hydrochloric acid by titrating it against
standard sodium carbonate solution.
F.
Determination of one anion and one cation in a given salt
Cations – Pb
Mg
4
Anions – CO
(Note : Insoluble salts excluded)
Project
Scientific investigations involving laboratory testing and collecting information from other sources.
A few suggested projects
• Checking the bacterial contamination in drinking water by testing sulphide ions.
• Study of the methods of purification of water.
• Testing the hardness, presence of iron, fluoride, chloride etc. depending upon the regional
variation in drinking water and the study of causes of presences of these ions above
permissible limit (if any)
• Investigation of the foaming capacity of different washing soaps and the effect of addition of
sodium carbonate on them.
• Study of the acidity of different samples of the tea leaves.
• Determination of the rate of evaporation of different liquids.
• Study of the effect of acids and bases on the tensile strength of fibers.
• Analysis of fruit and vegetable juices for their acidity.
Note:
with the approval of the teacher.
Theory Total Periods 60
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic
solids, amorphous and crystalline solids (elementary idea), unit cell in two dimensional and three
dimensional lattices, calculation of density of unit cell, packing in solids, voids, number of atoms
per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.
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Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases
in liquids, solid solutions, colligative properties – relative lowering of vapour pressure, elevation of
B.P., depression of freezing point, osmotic pressure, determination of molecular masses using
colligative properties, abnormal molecular mass.
Redox reactions; conductance in electrolytic solutions, specific and molar conductivity variations
of conductivity with concentration, Kohlrausch’s Law, electrolysis and laws of electrolysis
(elementary idea), dry cell – electrolytic cells and Galvanic cells; lead accumulator, EMF of a
cell, standard electrode potential, Nernst equation and its application to chemical cells, fuel
cells; corrosion.
Rate of a reaction (average and instantaneous), factors affecting rates of reaction: concentration,
temperature, catalyst; order and molecularity of a reaction; rate law and specific rate constant,
integrated rate equations and half life (only for zero and first order reactions); concept of collision
theory (elementary idea, no mathematical treatment).
Adsorption
catalysis: homogenous and heterogeneous, activity and selectivity: enzyme catalysis; colloidal state:
distinction between true solutions, colloids and suspensions; lyophillic, lyophobic multimolecular
and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement,
electrophoresis, coagulation; emulsions – types of emulsions.
Principles and methods of extraction
refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.
Group 15 elements
trends in physical and chemical properties; nitrogen – preparation, properties and uses; compounds
of nitrogen: preparation and properties of ammonia and nitric acid, oxides of nitrogen (structure
only); Phosphorous – allotropic forms; compounds of phosphorous: preparation and properties
of phosphine, halides (PCl
Group 16 elements
trends in physical and chemical properties; dioxygen: preparation, properties and uses; simple
oxides; ozone. Sulphur – allotropic forms; compounds of sulphur: preparation, properties and
uses of sulphur dioxide; sulphuric acid: industrial process of manufacture, properties and uses,
oxoacids of sulphur (structures only).
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Group 17 elements
trends in physical and chemical properties; compounds of halogens: preparation, properties
and uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens
(structures only).
Group 18 elements
and chemical properties, uses.
General introduction, electronic configuration, occurrence and characteristics of transition metals,
general trends in properties of the first row transition metals – metallic character, ionization
enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial
compounds, alloy formation. Preparation and properties of K
Lanthanoids
contraction.
Actinoids
Coordination compounds
and shapes, IUPAC nomenclature of mononuclear coordination compounds, bonding;
isomerism, importance of coordination compounds (in qualitative analysis, extraction of
metals and biological systems).
Haloalkanes
of substitution reactions.
Haloarenes
monosubstituted compounds only).
Uses and environmental effects of – dichloromethane, trichloromethane, tetrochloromethane,
iodoform, freons, DDT.
Alcohols
alcohols only); identification of primary, secondary and tertiary alcohols;
mechanism of dehydration, uses, some important compounds –
methanol and ethanol.
Phenols
chemical properties, acidic nature of phenol, electrophillic
substitution reactions, uses of phenols.
Ethers
30
and Carboxylic Acids
Aldehydes and Ketones
nature of carbonyl group, methods
of preparation, physical and chemical properties,
and mechanism of nucleophilic addition,
reactivity of alpha hydrogen in aldehydes; uses.
Carboxylic Acids
physical and chemical properties; uses.
Amines
properties, uses, identification of primary secondary and tertiary amines.
Cyanides and Isocyanides
Diazonium salts
Carbohydrates
oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen);
importance.
Proteins
structure, secondary structure, tertiary structure and quaternary structure (qualitative idea only),
denaturation of proteins; enzymes.
Vitamins
Nucleic Acids
Unit XV:
Classification
copolymerization. Some important polymers: natural and synthetic like polythene, nylon, polyesters,
bakelite, rubber.
Unit XVI:
1. Chemicals in medicines – analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials,
antifertility drugs, antibiotics, antacids, antihistamines.
2. Chemicals in food – preservatives, artificial sweetening agents.
3. Cleansing agents – soaps and detergents, cleansing action.
Microchemical methods are available for several of the practical experiments. Wherever possible
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(a) Preparation of one lyophilic and one lyophobic sol.
Lyophilic sol
Lyophobic sol
(b) Dialysis of sol prepared in (a) above.
(c) Study of the role of emulsifying agent in stabilizing the emulsions of different oils.
(a) Effect of concentration and temperature on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
(b) Study of reaction rates of any one of the following:
(i) Reaction of iodide ion with hydrogen peroxide at room temperature using different
concentration of iodide ions.
(ii) Reaction between potassium iodate (KIO
starch solution as indicator (clock reaction).
Any one of the following experiments:
(a) Enthalpy of dissolution of copper sulphate or potassium nitrate.
(b) Enthalpy of neutralization of strong acid (HCl) and strong base (NaOH).
(c) Determination of enthalpy change during interaction (Hydrogen bond formation) between
acetone and chloroform.
Variation of cell potential in Zn/Zn
(CuSO
(a) Separation of pigments from extracts of leaves and flowers by paper chromatography
and determination of R
(b) Separation of constituents present in an inorganic mixture containing two cations only
(constituents having wide difference in R
(a) Preparation of double salt of ferrous ammonium sulphate or potash alum.
(b) Preparation of potassium ferric oxalate.
G.
Preparation of any one of the following compounds:
(a) Acetanilide
(b) Di-benzal acetone
32
(c)
(d) Aniline yellow or 2-Napththol aniline dye.
H.
Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (primary) groups.
I.
Presence in given Food Stuffs
J.
against a Standard Solution of
(a) Oxalic acid
(b) Ferrous ammonium sulphate
(Students will be required to prepare standard solutions by weighing themselves).
K.
Determination of one anion and one cation in a given salt.
Project (Periods 10)
• Study of presence of oxalate ions in guava fruit at different stages of ripening.
• Study of quantity of casein present in different samples of milk.
• Preparation of soybean milk and its comparison with the natural milk with respect to curd
formation, effect of temperature, etc.
• Study of the effect of potassium bisulphate as food preservative under various conditions
(temperature, concentration, time etc.)
• Study of digestion of starch by salivary amylase and effect of pH and temperature on it.
• Comparative study of the rate of fermentation of following materials: wheat flour, gram
flour, potato juice, carrot juice etc.
• Extraction of essential oils present in
• Study of common food adulterants in fat, oil, butter, sugar, turmeric powder, chilli powder
and pepper.
Note