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sharma_shweta (0)

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how can we differentiate 2-nitro propane&1-nitro propane

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smriti.mathur (442)

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1-nitro propane is,
CH 3-CH2 -CH2 -NO2
and,
2-nitro propane is,
CH3 -CH-CH3
        I
        NO2

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rahul_c (188)

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treat
1-nitro propane is,
CH 3-CH2 -CH2 -NO2
and,
2-nitro propane is,
CH3 -CH-CH3
        I
        NO2
 
 
 
 
 
 
with Sn /HCL A WHICH WILL CONVERT IT TO AMINES . THEN WE HAVE TO TREAT WITH DILUTE NITROUS ACID WHICH CONVERT NH2 GROUP TO DIAZONIUM SALT  WHICH WHEN TREATED WITH WATER WILL FORM OH GROUP. THEN WE PERFORM VICTOR MEYER'S TEST TO DIFFERENTIATE 1 DEGREE AND 2 DEGREE ALCOHOL



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aditya_arora04 (1077)

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Well Shweta, you may also do it by Hinsberg test { it is well explained in almost every book }

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207aaa134 (2)

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AFTER CONVERTING TO NH2;
REACT WITH HNO2.--->GIVEN IN NCERT
 
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