solution::
moles of Cl- prepared = 0.072/2 = 0.036 moles
1 mole BaCl2.2H2O gives 2 moles of Cl-
=> 1 moles of Cl- will be given by 1/2 mole of BaCl2.2H2O
=> 0.036 moles of Cl- will be given by 0.036/2 = 0.018 moles of BaCl2.2H2O
=> mass of BaCl2.2H2O required = 244 * 0.018 = 4.392g (ans.)